The Ka expression for the H,PO,/HPO;- buffer is given by the equation Ionic strength (µ, M) 0.005 0.010 0.050 | 0.10 YH* 0.933 0.914 0.86 0.83 [HPO-] YHPO;- [H*] YH* Ка [H,PO,] YH,PO; YHPO; 0.740 0.660 0.445 0.355 = 10-7.20 YH, PO, 0.928 0.902| 0.82 |0.775 What is the pH of a 3:4 mixture of H, PO, to HPO;- at an ionic strength of 0.005 M? Activity coefficients can be found in the table. pH = 6.994

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The Ka expression for the H,PO,/HPO? - buffer is given
by the equation
Ionic strength (µ, M)
0.005 0.010 0.050 0.10
YH*
0.933 0.914 | 0.86
0.83
[HPO}-] Yuro; [H*] YH"
Ка
[H,PO] YH,PO,
YHPO;
0.740 0.660| 0.445 0.355
= 10-7.20
YH, PO,
0.928 0.902 0.82 0.775
What is the pH of a 3:4 mixture of H, PO, to HPO- at an
2
ionic strength of 0.005 M? Activity coefficients can be
found in the table.
pH =
6.994
Transcribed Image Text:The Ka expression for the H,PO,/HPO? - buffer is given by the equation Ionic strength (µ, M) 0.005 0.010 0.050 0.10 YH* 0.933 0.914 | 0.86 0.83 [HPO}-] Yuro; [H*] YH" Ка [H,PO] YH,PO, YHPO; 0.740 0.660| 0.445 0.355 = 10-7.20 YH, PO, 0.928 0.902 0.82 0.775 What is the pH of a 3:4 mixture of H, PO, to HPO- at an 2 ionic strength of 0.005 M? Activity coefficients can be found in the table. pH = 6.994
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