The kinetics of the reaction: I⁻ + OCl⁻ ⇄ OI⁻ + Cl⁻ was studied in basic aqueous media by Chia and Connick . The initial rate of I⁻ disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI⁻ or Cl⁻ ). If the mechanism of the reaction is given below, which constants below play role in the reaction rate law: OCl⁻ + H₂O ⇄ HOCl + OH⁻ (rate constant=k₁, equil.const=K₁)---fast, equilibrium I⁻ + HOCl → HOI + Cl⁻ (rateconstant=k₂)---slow HOI + OH⁻ ⇄ H₂O + OI⁻ (rate constant=k₃, equil.const=K₂)---fast, equilibrium

The kinetics of the reaction: I⁻ + OCl⁻ ⇄ OI⁻ + Cl⁻ was studied in basic aqueous media by Chia and Connick . The initial rate of I⁻ disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI⁻ or Cl⁻ ). If the mechanism of the reaction is given below, which constants below play role in the reaction rate law: OCl⁻ + H₂O ⇄ HOCl + OH⁻ (rate constant=k₁, equil.const=K₁)---fast, equilibrium I⁻ + HOCl → HOI + Cl⁻ (rateconstant=k₂)---slow HOI + OH⁻ ⇄ H₂O + OI⁻ (rate constant=k₃, equil.const=K₂)---fast, equilibrium

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter33: High-performance Liquid Chromatography

Section: Chapter Questions

Problem 33.14QAP

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