The pK, of monobasic phosophate is 7.21 H,PO,=HPO +H* K, = 10721 at infinite dilution. However, most practical phosphate buffers have a significant ionic strength. Let's say we made a phosphate buffer in a solution with an ionic strength of 0.05 M. Please calculate the new conditional pk, value, adjusted to this ionic strength. Note that the answer should be pK, and not K,

The pK, of monobasic phosophate is 7.21 H,PO,=HPO +H* K, = 10721 at infinite dilution. However, most practical phosphate buffers have a significant ionic strength. Let's say we made a phosphate buffer in a solution with an ionic strength of 0.05 M. Please calculate the new conditional pk, value, adjusted to this ionic strength. Note that the answer should be pK, and not K,

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

The Ksp of CaC2O4 at 298 K is 2.30×10-9. Determine the molar solubility of this salt.
Determine the solubility of KIO4 in water. Volume of saturated KIO4 in conical flask is 25.0 ml,KI is 2g,H2SO4 (3.0M) is 20.0 ml added to KI solution , volume of 0.200 M sodium thiosulphate used for titration is 8.00 ml.and if mean ionic activity co efficient,y+- of KIO4 in the saturated solution is 0.85 ,what is Ksp. .
. At 250C, Ksp for AgBr is 5.0 x 10-13. Calculate the solubility of AgBr in g/L at 25 oC (a) in pure water; (b) In the presence of 0.2 mol L−1 NaBr solution
Calculate the solubility of lead(II) sulfate (Ksp = 2.53x10-8) in a 0.0034 M solution of sodium sulfate. Give your answer to three sig. figs. and in exponential form (e. g. 1.23E-3).
To determine the concentration of glucose in the packaged juice industry, 50 mL of sample is analyzed. Analysis of it (and other reducing sugars) was carried out there using triiodide back titration. An excess volume of 75.00 mL of 0.338 M triiodide standard solution in alkaline medium was added to the glucose solution. The resulting solution was acidified and the excess triiodide was titrated with 18.37 mL of standard 0.526 M thiosulfate solution. Calculate is the concentration in ppm in the sample. In alkaline medium: Glucose (C6H12O6) / Gluconate (C6H11O7-), Triiodide (I3- ) / Iodide (I-) In acid medium: Thiosulfate (S2O32-) / Tetrathionate (S4O62-), Triiodide (I3- ) / Iodide (I-)
1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.
Calculate the solubility (in g/L) of silver chromate in water at 25°C if the Ksp for Ag3PO4 is 1.75 × 10-18. Ag3PO4(s) <==> 3Ag+ (aq) + PO43- (aq); Ksp = 27s4, s = _________ mol/L x MM of Ag3PO4 = _________ g/L.
The reaction A(g) + B(g) ↔ C(g) + D(g) has ΔGrxn° = -28.62 kJ mol-1 and Kp = 0.63 at 980 °C. A rigid cylinder at that temperature contains 1.2 atm of A, 0.20 atm of B, 0.30 atm of C, and 0.27 atm of D. What is the reaction Gibbs energy?
For titration for determination of Chloride, 0.05 AgNO3 and NaCl with a 5% (w/v) K2CrO4 indicator, what is the % (w/w) Cl- using the atomic weight for Chlorine. Data below: Primary standard weight 0.1173g , 0.1056g , and 0.1049g Vol of titrant delivered 35.47mL , 31.75mL, and 31.04mL Uknown Chloride mass 0.1527g, 0.1442g, and 0.1337g Vol of titrant delivered 40.00mL ,37.68mL ,and 34.96 mL
A mixture of NaBr, Nal and NaNO3 weighs 0.6500 g. With AgNO3, a precipitate of the two halides is obtained and is found to weigh 0.9390 g. When heated in a current of C2, the precipitate is converted entirely to AgCi weighing 0.6566 g. What is the %NaNO3 in the original sample?
Calculate the solubility (in g/L) of Aluminum sulfide (Al2S3) at 25°C {Ksp for Al2S3 is 1.5x10^-27}. 1) in pure water 2) in 0.10 M H2S solution and in 0.25M Al^+3 solution
In an experiment to determine the concentration of H2SO4 in a brand of toilet cleanser, 10.0 cm3 of the cleanser was first diluted to 250.0 cm3 with distilled water. 25.0 cm3 of the diluted cleanser were titrated with 0.320 mol dm–3 NaOH solution, using methyl orange as indicator.If 29.2 cm3 of NaOH solution is used, what is the concentration of H2SO4 in the undiluted toilet cleanser?a. 2.30 mol dm–3b. 4.60 mol dm–3 c. 9.20 mol dm–3 d. 11.50 mol dm–3