The reaction between fluorine and chlorine dioxide, F2(g) + ClO2(g) → 2FClO2(g) Proceeds according to the following rate Law: r=k⋅PF2⋅PClO2 where k= 0.0489 bar-1 s-1. In an isolation experiment, the initial partial pressures are: PF2(t=0) = 0.04687 bar and   PClO2(t=0) = 3.606 bar.   Note: Ukeff   means units of keff . You need to use a string with no spaces. For example enter gm3   as g*m^{-3} or g/m^3 . (a) Calculate the effective rate constant keff=  Ukeff=  (b) Compute the pressure of fluorine in bar after 55.8 s. PF2(t=55.8s)=  bar (c) How long will it take for the pressure of fluorine to drop to 0.01318 bar?   t =    s

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Chapter12: Chemical Kinetics
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The reaction between fluorine and chlorine dioxide,

F2(g) + ClO2(g) → 2FClO2(g)

Proceeds according to the following rate Law: r=k⋅PF2⋅PClO2

where k= 0.0489 bar-1 s-1. In an isolation experiment, the initial partial pressures are:

PF2(t=0) = 0.04687 bar and   PClO2(t=0) = 3.606 bar.   Note: Ukeff   means units of keff . You need to use a string with no spaces. For example enter gm3   as g*m^{-3} or g/m^3 .

(a) Calculate the effective rate constant keff=  Ukeff= 

(b) Compute the pressure of fluorine in bar after 55.8 s. PF2(t=55.8s)=  bar

(c) How long will it take for the pressure of fluorine to drop to 0.01318 bar?   t =    s

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