The toluene proton NMR spectrum, consisting of two peaks due to the methyl and aromatic protons, has been recorded at 55.0 MHz and 1.29 T. (a) What would the magnetic field be at 500. MHz? 4.0 (b) At 55.0 MHz, the resonance frequencies are methyl: 128 Hz; aromatic: 394 Hz. What would the frequencies be using a 500. MHz spectrometer? methyl 4.0 Hz aromatic 4.0 Hz (c) Calculate the chemical shifts (8) of the two signals, using both the 55.0 MHz and 500. MHz data. methyl at 55.0 MHz 4.0 ppm aromatic at 55.0 MHz 4.0 ppm methyl at 500. MHz 4.0 ppm aromatic at 500. MHz 4.0 ppm

EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter95: Nuclear Magnetic Resonance Spectroscopy (proton Nmr)
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The toluene proton NMR spectrum, consisting of two peaks due to the methyl and aromatic protons, has been recorded at 55.0 MHz and 1.29 T.
(a) What would the magnetic field be at 500. MHz?
4.0
(b) At 55.0 MHz, the resonance frequencies are methyl: 128 Hz; aromatic: 394 Hz. What would the frequencies be using a 500. MHz spectrometer?
methyl
[4.0
Hz
aromatic
4.0
Hz
(c) Calculate the chemical shifts (8) of the two signals, using both the 55.0 MHz and 500. MHz data.
methyl at 55.0 MHz
4.0
ppm
4.0
aromatic at 55.0 MHz
ppm
methyl at 500. MHz
4.0
ppm
aromatic at 500. MHz
4.0
ppm
Transcribed Image Text:The toluene proton NMR spectrum, consisting of two peaks due to the methyl and aromatic protons, has been recorded at 55.0 MHz and 1.29 T. (a) What would the magnetic field be at 500. MHz? 4.0 (b) At 55.0 MHz, the resonance frequencies are methyl: 128 Hz; aromatic: 394 Hz. What would the frequencies be using a 500. MHz spectrometer? methyl [4.0 Hz aromatic 4.0 Hz (c) Calculate the chemical shifts (8) of the two signals, using both the 55.0 MHz and 500. MHz data. methyl at 55.0 MHz 4.0 ppm 4.0 aromatic at 55.0 MHz ppm methyl at 500. MHz 4.0 ppm aromatic at 500. MHz 4.0 ppm
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