The vibrational frequency of the hydrogen chloride HCI diatomic molecule is 8.97 x 1013 Hz. chloride atom is 35.5 times more massive than hydrogen atom. (my = 1.67 x 0-27 kg,c = 3.0 x 10°m/s) a) What is the force constant of the molecular bond between the hydrogen and the chloride atoms? b) What is the energy of the emitted photon when this molecule makes a transition between adjacent vibrational energy levels? c) What is the wavelength of the emitted photon?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
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The vibrational frequency of the hydrogen chloride HCl diatomic molecule is 8.97 x 1013Hz. chloride atom is
35.5 times more massive than hydrogen atom. (mµ = 1.67 x 0-27kg,c = 3.0 x 10°m/s)
a) What is the force constant of the molecular bond between the hydrogen and the chloride atoms?
b) What is the energy of the emitted photon when this molecule makes a transition between adjacent
vibrational energy levels?
c) What is the wavelength of the emitted photon?
d) The possible wavelengths of photons emitted with the HCl molecule decays from the 2nd excited state
eventually to the ground state(0 state).
Transcribed Image Text:The vibrational frequency of the hydrogen chloride HCl diatomic molecule is 8.97 x 1013Hz. chloride atom is 35.5 times more massive than hydrogen atom. (mµ = 1.67 x 0-27kg,c = 3.0 x 10°m/s) a) What is the force constant of the molecular bond between the hydrogen and the chloride atoms? b) What is the energy of the emitted photon when this molecule makes a transition between adjacent vibrational energy levels? c) What is the wavelength of the emitted photon? d) The possible wavelengths of photons emitted with the HCl molecule decays from the 2nd excited state eventually to the ground state(0 state).
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