To determine the equilibrium separation of the atoms in the HCl molecule, you measure the rotational spectrum of HCl. You find that the spectrum contains these wavelengths (among others): 60.4 mm, 69.0 mm, 80.4 mm, 96.4 mm, and 120.4 mm. (a) Use your measured wavelengths to find the moment of inertia of the HCl molecule about an axis through the center of mass and perpendicular to the line joining the two nuclei. (b) The value of l changes by +-1 in rotational transitions. What value of l for the upper level of the transition gives rise to each of these wavelengths? (c) Use your result of part (a) to calculate the equilibrium separation of the atoms in the HCl molecule. The mass of a chlorine atom is 5.81 * 10-26 kg, and the mass of a hydrogen atom is 1.67 * 10-27 kg. (d) What is the longest-wavelength line in the rotational spectrum of HCl?

Physics for Scientists and Engineers with Modern Physics
10th Edition
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Raymond A. Serway, John W. Jewett
Chapter42: Molecules And Solids
Section: Chapter Questions
Problem 13P
icon
Related questions
Question

To determine the equilibrium separation of the atoms in the HCl molecule, you measure the rotational spectrum of HCl. You find that the spectrum contains these wavelengths (among others): 60.4 mm, 69.0 mm, 80.4 mm, 96.4 mm, and 120.4 mm. (a) Use your measured wavelengths to find the moment of inertia of the HCl molecule about an axis through the center of mass and perpendicular to the line joining the two nuclei. (b) The value of l changes by +-1 in rotational transitions. What value of l for the upper level of the transition gives rise to each of these wavelengths? (c) Use your result of part (a) to calculate the equilibrium separation of the atoms in the HCl molecule. The mass of a chlorine atom is 5.81 * 10-26 kg, and the mass of a hydrogen atom is 1.67 * 10-27 kg. (d) What is the longest-wavelength line in the rotational spectrum of HCl?

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 5 steps

Blurred answer
Knowledge Booster
Gibbs free Energy
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, physics and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Physics for Scientists and Engineers with Modern …
Physics for Scientists and Engineers with Modern …
Physics
ISBN:
9781337553292
Author:
Raymond A. Serway, John W. Jewett
Publisher:
Cengage Learning
Modern Physics
Modern Physics
Physics
ISBN:
9781111794378
Author:
Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:
Cengage Learning