Use the Boltzmann equation to find the relative number of atoms or molecules in the excited state for each of the following transitions at room temperature (Assume that gi/ go is 1 for all transitions). a. Electronic transition with an emission of 280 nm (UV) b. Electronic transitions with an emission of 6700 A (red visible light) c. Vibrational transition with a frequency of 2500 waves/cm (Mid IR) d. A rotational transition with a 2.45 GHz (microwave oven frequency) e. An NMR transition with a frequency of 60 MHz
Use the Boltzmann equation to find the relative number of atoms or molecules in the excited state for each of the following transitions at room temperature (Assume that gi/ go is 1 for all transitions). a. Electronic transition with an emission of 280 nm (UV) b. Electronic transitions with an emission of 6700 A (red visible light) c. Vibrational transition with a frequency of 2500 waves/cm (Mid IR) d. A rotational transition with a 2.45 GHz (microwave oven frequency) e. An NMR transition with a frequency of 60 MHz
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter6: Electronic Structure And The Periodic Table
Section: Chapter Questions
Problem 66QAP: Consider the following transitions 1. n=3 to n=1 2. n=2 to n=33. n=4 to n=34. n=3 to n=5(a) For...
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Please explain how to use Boltzmann equation for these problems.
Transcribed Image Text:Use the Boltzmann equation to find the relative number of atoms or molecules in the
excited state for each of the following transitions at room temperature (Assume that gi/
go is 1 for all transitions).
a. Electronic transition with an emission of 280 nm (UV)
b. Electronic transitions with an emission of 6700 A (red visible light)
c. Vibrational transition with a frequency of 2500 waves/cm (Mid IR)
d. A rotational transition with a 2.45 GHz (microwave oven frequency)
e. An NMR transition with a frequency of 60 MHz
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