What is the value of Kf for the formation of the ammine M(NH3)2? Assume the concentration of M(NH3)n* = 0.0020 M The data were graphed giving a straight line plot with an equation of y = -5.9484x - 9.26. .
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Q: What is the value of Kf for the formation of the ammine M(NH3)2? Assume the concentration of…
A: The concentration of M(NH3)n+ = 0.0020 M The straight line equation is y = - 5.9484 x – 9.26. X =…
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- Caustic potash that has been exposed to air is found on analysis to contain 90.00% KOH, 2.38% K2CO3 and 7.62% H2O. What weight of residue will be obtained if 1.00 g of this sample is added to 46.00 mL of 1.00 N HCl and the resulting solution, after neutralization with 1.070N KOH is evaporated to dryness?A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br-Nickel ion required 11.70 mL of 0.002146 M EDTAWhat is the percentage of NaBr (102.894) in the 1.000 g sample?When I was a boy, I watched Uncle Wilbur measure the iron content of runoff from his banana ranch. He acidified a 25.0-mL sample with HNO3 and treated it with excess KSCN to form a red complex. (KSCN itself is colorless.) He then diluted the solution to 100.0 mL and put it in a variablepathlength cell. For comparison, he treated a 10.0-mL reference sample of 6.80 3 1024 M Fe31 with HNO3 and KSCN and diluted it to 50.0 mL. The reference was placed in a cell with a 1.00-cm pathlength. Runoff had the same absorbance as the reference when the pathlength of the runoff cell was 2.48 cm. What was the concentration of iron in Uncle Wilbur’s runoff ?
- The accompanying data (1.00-cm cells) were obtained for the spectrophotometric titration 10.00 mL of Pd(II) with 2.44 10-4 M Nitroso R(O. W Rollins and M. M. Oldham, Anal. chem .,1971, 43, 262, DOI: 10.1021/ac60297a026). Calculate the concentration of the Pd(II) solution, given that the ligand-to-cation ratio in the colored product is 2:1A 0.1017 g sample of KBrO3 (MM=166.1) was dissolved in dilute HCI and treated with an unmeasured excess of Kl. The liberated iodine required 39.75 mL of Na₂S₂O3. Calculate the molar concentration of sodium thiosulfate. 0.2561 M 0.08512 M 0.09242 M 0.1041 MConsider an F M solution of Fe2(SO4)3. Besides H+ and OH−, the known species are Fe3+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, FeSO4+, SO42−, and HSO4−. a) Write the charge balance equation for this solution. b) Which species must be an ion pair, and which comes from acid hydrolysis of Fe3+? Write the balanced acid hydrolysis reaction for the hexa-aquo complex of Fe3+ and report its pKa c) Write two mass balance equations for this solution, one for total iron and one for total sulfate. [How do you think you should handle the species that includes two iron atoms?] Give numerical values for these equations in terms of F.
- A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br-50.00 mL remaining solution was analyzed for its Br- content by potentiometry using a metallic electrode of the second kind. a) Write the cell notation of the potentiometric set-up with SCE as the reference electrode. b) Write the Nernst equation that describes the indicator electrode set-up. Ecell recorded in running the solution using the potentiometric set-up was Ecell = 0.0286 V. (E0Ag/AgBr = 0.095 V) c) Compute for Eind. d) Compute pBr in the 50.00 mL aliquot. e) Compute for % NaBr ( in the potentiometric technique).Is it posible to remove 99% of 1.0 μM CuY2- impurity (by reduction to solid Cu) from a 10.0 mM CoY2- solution at pH 4.0 without reducing any cobalt? Here, Y (actually, Y4-) is EDTA and the total concentration of free EDTA is 10.0 mM. Hint: Concepts of Equilibrium of EDTA Complex Formation are involved in the solution of this problem. Standard reduction potentials to use in this problem are:CuY2- + 2e- ➙ Cu(s) + Y4- E°= -0.216 VCo2+ + 2e- ➙ Co(s) E°= -0.282 V.A sample is analyzed for chloride by the Volhard method. Calculate the %KCl from the following data: Wt of sample = 0.5000g; Vol of AgNO3 added = 35.00ml; M of AgNO3 = 0.1157; Vol of SCN- used for back titration = 14.71ml; M of SCN- = 0.08598; Atomic wts: Ag = 107.87, N = 14.00, Cl = 35.5, O = 16.00
- If (1.7479x10^-6) mol of CaCO3 (calcite) and (5.91x10^-8) mol CaSO4•2H2O (gypsum) were to completely dissolve in 1 L of water, what would the ion activity product of CaCO3 be? Assume activity is equal to concentration & round to 3 significant figures.What is the percentage of Nickel in an ore if, when analyzed by the cyanide method, 20.00mL of KCN solution (containing 1.00mmol of AgNO3 per milliliter) are used? Wt of sample used = 0.2500gA 1.000 g sample containing chlorides, iodides and inert materials was treated with dilute nitric acid followed by AgNO3. A precipitate of AgCl (143.32) and AgI (234.77) was produced and weighs 0.9238 g. On heating in a current of Cl2, the AgI is converted to AgCl, and the resulting product weighs 0.7238 g. Find the percentage of a) NaI (149.89) and b) NaCl (58.44) in the sample