When 2-methylnaphthalene undergoes an irreversible electrophilic aromatic substitution, the electrophile predominantly attaches to the 1 position instead of the 3 position. This suggests that the arenium ion that is formed from attachment of the electrophile to the 1 position is more stable than the arenium ion formed from attachment of the electrophile to the 3 position. Explain why this is so. Hint: Simple resonance theory can explain why. CH3 CH3 CH3 + 2-Methylnaphthalene Major product

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 12E
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When 2-methylnaphthalene undergoes an irreversible electrophilic aromatic substitution, the electrophile predominantly
attaches to the 1 position instead of the 3 position. This suggests that the arenium ion that is formed from attachment
of the electrophile to the 1 position is more stable than the arenium ion formed from attachment of the electrophile to
the 3 position. Explain why this is so. Hint: Simple resonance theory can explain why.
CH3
CH3
CH3
+
2-Methylnaphthalene
Major product
Transcribed Image Text:When 2-methylnaphthalene undergoes an irreversible electrophilic aromatic substitution, the electrophile predominantly attaches to the 1 position instead of the 3 position. This suggests that the arenium ion that is formed from attachment of the electrophile to the 1 position is more stable than the arenium ion formed from attachment of the electrophile to the 3 position. Explain why this is so. Hint: Simple resonance theory can explain why. CH3 CH3 CH3 + 2-Methylnaphthalene Major product
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