When a metal ion precipitates out of solution before it can be bound to EDTA in a quantitative titration, a(n) _______ is used to keep the metal ion in solution. masking agent fugacity coefficient multidentate ligand auxiliary competing agent metal ion indicator
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- masking agent
- fugacity coefficient
- multidentate ligand
- auxiliary competing agent
- metal ion indicator
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- Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided Determination of water hardness using complexometric titration. During sample analysis (ppm CaCO3), the volume for blank correction was not subtracted to the volume of titrant. EX Blank 1 ETSources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided TOPIC: Measured mass of the precipitate 1. Filter paper was dried prior to filtration. EX _____ ET TOPIC: Standardization of Titrant 2. Distilled water was not equilibrated to room temperature before the preparation of NaOH titrant. EX ______ ET TOPIC: Determination of Molar Concentration of each component (Double Indicator Titration) 3. No blank correction EX ______ ETAn auxiliary competing agent is used in EDTA titrations to slow down the titration. keep some interfering component of the analyte mixture from complexing with the EDTA. speed up the titration. keep the metal ion from precipitating out of the solution.
- 1. These are balances that have a maximum loading of 10 to 30 g with a precision of 60.01 mgA. semi-microanalyticalB. MicroanalyticalC. MacrobalancesD. Triple Beam Balance2. Which type of curve is normally produced when plotting the change in the concentration of a specie of some function and the amount of reagent added?A. Titration curveB. Sigmoidal CurveC. Phase Transition curveD. Calibration curve3. In the dead dear case study, silver diethyldithiocarbamateforms a colored solution when it binds with arsenic, what do we call substance like silver diethyldithiocarbamate?A. Secondary standard reagentB. Precipitating agentC. Chelating agentD. Primary standard reagent1. What is the type of titration is involved this method? Direct Indirect Residual Blank 2. What is the weight (in grams) to be used? 3. What is the molecular weight to be used? 4. What is the computed molar concentration of EDTA?Which is CORRECT? a. EDTA has 2 oxygen sites and 2 nitrogen sites that are electron rich. b. At pH = 10, fraction of fully deprotonated form of EDTA approaches to 1. c. EDTA titrations that are carried out beyond pH 10 typically involves the use of auxiliary reagents. d. As long as EDTA titrations are carried out beyond pH 10, we are sure that all of the analyte will react completely with EDTA.
- If the water sample used for titration was buffered with acid instead of alkali, the amount of EDTA required to reach the endpoint will: a. stay constant b. be indeterminatec. increased. decreaseThe water hardness of tap water has been determined to be 120 (= 120 mg CaCO3 per 1 L of water). After the tap water has run through the ion exchange column, titration of a 20.00 mL sample used only 0.70 mL of 0.0100 M EDTA, to reach the endpoint. Calculate the effectiveness of the ion exchange column: what is the % of the calcium, removed by the ion exchange column? Provide your answer in % and without decimal. ( Please type answer note write by hend)2,5 ml volume has taken from an “hypothetic” solution which includes (3+) Sb and (3+) Fe and at the titration with 0.1004 N KMnO4, the wasted amount has found as 16,4 mL. The other 2,5 mL that has taken, has reduced with Zn after that, this 2,5 mL solution has titrates with the same KMnO4 solution solution and the wasted amount is 26,5mL. With these datas find the %concentrations of the ions at the solution.
- Advantages of potentiometric titrations over 'classical' visual indicator methods: (select the correct statement(s)). Can be used for colored, turbid or fluorescent analyte solution. Can be used if there is no suitable indicator or if the color change is difficult to visualize. Both answers 1 and 2 are correctData Table for Weak Acid Vol. of Titrant pH Avg. Vol. ∆pH/∆vol 0 2.881 0.25 0.622575 0.5 3.193 0.75 0.453769 1 3.420 1.25 0.32668 1.5 3.583 1.75 0.251434 2 3.709 2.25 0.20456 2.5 3.811 2.75 0.173202 3 3.897 3.25 0.150977 3.5 3.973 3.75 0.134517 4 4.040 4.25 0.12191 4.5 4.101 4.75 0.112002 5 4.157 5.25 0.104057 5.5 4.209 5.75 0.097586 6 4.258 6.25 0.092253 6.5 4.304 6.75 0.087819 7 4.348 7.25 0.084111 7.5 4.390 7.75 0.081001 8 4.431 8.25 0.078391 8.5 4.470 8.75 0.076209 9 4.508 9.25 0.074397 9.5 4.545 9.75 0.072912 10 4.582 10.25 0.071719 10.5 4.617 10.75 0.070794 11 4.653 11.25 0.070117 11.5 4.688 11.75 0.069675 12 4.723 12.25 0.06946 12.5 4.757 12.75 0.069467 13 4.792 13.25 0.069696 13.5 4.827 13.75 0.070152 14 4.862 14.25 0.070845 14.5 4.897 14.75 0.071787 15 4.933 15.25 0.072999 15.5 4.970 15.75 0.074507 16 5.007 16.25 0.076346 16.5 5.045 16.75 0.078561 17 5.085 17.25 0.081211 17.5 5.125 17.75 0.084372 18…Sources of Error Determine the relationship between the observed/apparent value (EX) VERSUS that of the true value (ET) for the quantity being sought by writing either <, >, or = on the space provided TOPIC: Measured mass of the precipitate Question 4 Overignition which causes the conversion of BaSO4 precipitate to BaO. EX ___ ET Question 5 Precipitate was not washed thoroughly. Ex ___ ET TOPIC: Standardization of Titrant Question 6 Adding insufficient amount of titrant to reach acceptable endpoint color: EX ___ ET