Which statement is incorrect about CO ligands? a. A CO ligand can accept electrons into its * MO; this weakens the C-O bond b. In the IR spectrum of Fe(CO)5, absorptions assigned to the CO stretching modes are at higher wavenumber than that of free c. CO ligands can adopt terminal, p2 and u3 bonding modes; the amount of back donation depends on the bonding mode d. Fluxional behaviour is common in metal carbonyl compounds, and can be investigated by 13C NMR spectroscopy

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
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Which statement is incorrect about CO ligands?
a. A CO ligand can accept electrons into its * MO; this weakens the C-O bond
b. In the IR spectrum of Fe(CO)5, absorptions assigned to the CO stretching modes are at higher wavenumber than that of free
c. CO ligands can adopt terminal, p2 and u3 bonding modes; the amount of back donation depends on the bonding mode
d.
Fluxional behaviour is common in metal carbonyl compounds, and can be investigated by 13C NMR spectroscopy
Transcribed Image Text:Which statement is incorrect about CO ligands? a. A CO ligand can accept electrons into its * MO; this weakens the C-O bond b. In the IR spectrum of Fe(CO)5, absorptions assigned to the CO stretching modes are at higher wavenumber than that of free c. CO ligands can adopt terminal, p2 and u3 bonding modes; the amount of back donation depends on the bonding mode d. Fluxional behaviour is common in metal carbonyl compounds, and can be investigated by 13C NMR spectroscopy
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