Why does scanning not start at the excitation wavelength in fluorescence spectroscopy?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter16: Introduction To Magnetic Spectroscopy
Section: Chapter Questions
Problem 16.16E
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Why does scanning not start at the excitation wavelength in fluorescence spectroscopy?

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