A.) Which parameter between "solvent polarity function" and dielectric constant show better correlation with the peak positions?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
ChapterL3: Carbon (13c) Nmr Spectroscopy
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A.) Which parameter between "solvent polarity function" and dielectric constant show better correlation with the peak positions?

B.) When a chromophore binds to proteins, the binding site is generally more hydrophobic than the solution. Then, what kind of shift do you expect to observe in the absorption peak position compared to the peak observed when the chromophore is free in solution?

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