You find an old, 3-L pressurized bottle of Freon 12 (dichlorodifluoromethane, CCl2F2, MW= 120.91 g/mol) at a dump site with a gauge indicating 2.7 atm of pressure. The temperature is 10° C. How much Freon 12 is still remains in the bottle? The following data are available: Tm = -158.0° C, Tb = -29.8° C). T C) P° (atm) CI -29.8 1 -12.2 16.1 42.4 74.0 2 "CI F F 10 20

You find an old, 3-L pressurized bottle of Freon 12 (dichlorodifluoromethane, CCl2F2, MW= 120.91 g/mol) at a dump site with a gauge indicating 2.7 atm of pressure. The temperature is 10° C. How much Freon 12 is still remains in the bottle? The following data are available: Tm = -158.0° C, Tb = -29.8° C). T C) P° (atm) CI -29.8 1 -12.2 16.1 42.4 74.0 2 "CI F F 10 20

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter5: Gases

Section: Chapter Questions

Problem 5.90PAE

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5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.
93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)
Butane, C4H10, is an easily liquefied gaseous fuel. Calculate the density of butane gas at 0.857 atm and 22C. Give the answer in grams per liter
5-115 Ammonium nitrite decomposes upon heating to form nitrogen gas and water vapor according to the following unbalanced chemical reaction: When a sample is decomposed in a test tube, 511 mL Of wet N2(g) is collected over water at 26°C and 745 torr total pressure. How many grams of dry NH4NO2(s) were initially decomposed? The vapor pressure of water at 26°C is 25.2 torr.
Uranium hexafluoride, UF6, is a white solid that sublimes (vaporizes without melting) at 57C under normal atmospheric pressure. The compound is used to separate uranium isotopes by effusion. What is the rms speed (in m/s) of a uranium hexafluoride molecule at 57C?
Earths atmosphere is approximately 80 N2 and 20 O2. If the total atmospheric pressure at sea level is about 14.7 lb/in2. where lb/in2 is pounds per square inch, a common but non-SI unit of pressure, what are the partial pressures of N2 and O2 in units lbs/in2?
A sample of a smoke stack emission was collected into a 1.25-L tank at 752 mm Hg and analyzed. The analysis showed 92% CO2, 3.6% NO, 1.2% SO2, and 4.1% H2O by mass. What is the partial pressure exerted by each gas?
61 As one step in its purification, nickel metal reacts with carbon monoxide to form a compound called nickel tetracarbonyl, Ni(CO)4, which is a gas at temperature above about 316 K. A 2.000-L flask is filled with CO gas to a pressure of 748 torr at 350.0 K, and then 5.00 g of Ni is added. If the reaction describe occurs and goes to completion at constant temperature, what will the final pressure in the falsk be?
109 An ore sample with a mass of 670 kg contains 27.7% magnesium carbonate, MgCO3. If all of the magnesium carbonate in this ore sample is decomposed to form carbon dioxide, describe how to determine what volume of CO2 is evolved during the process. What would have to be measured to predict the needed volume in advance?
105 The decomposition of mercury(II) thiocyanate produces an odd brown snake-like mass that is so unusual the process was once used in fireworks displays. There are actually several reactions that take place when the solid Hg(SCN)2 is ignited: 2Hg(SCN)2(s)2HgS(s)+CS2(s)+C3N4(s)CS2(s)+3O2(g)CO2(g)+2SO2(g)2C3N4(s)3(CN)2(g)+N2(g)HgS(s)+O2(g)Hg(l)+SO2(g) A 42.4-g sample of Hg(SCN)2 is placed into a 2.4-L vessel at 21°C. The vessel also contains air at a pressure of 758 torr. The container is sealed and the mixture is ignited, causing the reaction sequence above to occur. Once the reaction is complete, the container is cooled back to the original temperature of 21°C. (a) Without doing numerical calculations, predict whether the final pressure in the vessel will be greater than, less than, or equal to the initial pressure. Explain your answer. (b) Calculate the final pressure and compare your result with your prediction. (Assume that the mole fraction of O2 in air is 0.21.)
94 Mining engineers often have to deal with gases when planning for the excavation of coal. Some of these gases, including methane, can be captured and used as fuel to support the mining operation. For a particular mine, 2.4 g of CH4 is present for every 100.0 g of coal that is extracted. If 45.6% of the methane can be captured and the daily production of the mine is 580 metric tons of coal, how many moles of methane could be obtained per day?
Hydrogen azide, HN3, decomposes on heating by the following unbalanced equation: HN3O(g)N2(g)+H2(g) If 3.0 atm of pure HN3(g) is decomposed initially, what is the final total pressure in the reaction container? What are the partial pressures of nitrogen and hydrogen gas? Assume the volume and temperature of the reaction container are constant.

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