Inorganic Chemistry
5th Edition
ISBN: 9781292134147
Author: Housecroft, Catherine E.
Publisher: Pearson,
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Chapter 1, Problem 7P
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Chapter 1 Solutions
Inorganic Chemistry
Ch. 1 - Chromium has four isotopes C2450r, C2452r, C2453r...Ch. 1 - Prob. 2PCh. 1 - Using the list of naturally occurring isotopes in...Ch. 1 - Hydrogen possesses three isotopes, but tritium ,...Ch. 1 - (a) By using the data in appendix 5, account for...Ch. 1 - Calculate the corresponding wavelength of...Ch. 1 - State which of the following n'n transitions in...Ch. 1 - Calculate the energy (in kJ per mole of photons)...Ch. 1 - 1.9 Four of the lines in Balmer series are at...Ch. 1 - 1.10 Using the Bohr model, determine the values of...
Ch. 1 - 1.11 How is the (a) energy and (b) size of an ns...Ch. 1 - 1.12 Write down a set of quantum numbers that...Ch. 1 - Do the three 4p atomic orbitals possess the same...Ch. 1 - How many radial nodes does each of the following...Ch. 1 - 1.15 Comment on the differences between plots of...Ch. 1 - 1.16 Write down the sets of quantum numbers that...Ch. 1 - Write down the three sets of quantum numbers that...Ch. 1 - How many atomic orbitals make up the set with n=4...Ch. 1 - Prob. 19PCh. 1 - (a) Will a plot of R(r) for the 1s atomic orbital...Ch. 1 - Prob. 21PCh. 1 - Prob. 22PCh. 1 - Write down the six sets of quantum numbers that...Ch. 1 - For a neutral atom, X, the following atomic...Ch. 1 - Using the concepts of shielding and penetration,...Ch. 1 - For each of the following atoms, write down a...Ch. 1 - 1.27 Draw energy level diagrams (see Fig. 1.15) to...Ch. 1 - 1.28 Write down the ground state electronic...Ch. 1 - Write down (with reasoning) the ground state...Ch. 1 - Draw energy level diagrams to show the ground...Ch. 1 - The ground state electronic configuration of a...Ch. 1 - (a) Write down an equation that defines the...Ch. 1 - 1.33 The first four ionization energies of an atom...Ch. 1 - 1.34 In Fig. 1.16, identify the trend in the first...Ch. 1 - 1.35 Figure 1.17 shows the values of for the...Ch. 1 - Using the data in Table 1.5, determine a value for...Ch. 1 - Prob. 37PCh. 1 - What is the evidence that the aufbau principle is...Ch. 1 - The first list in the table on the left contains...Ch. 1 - Prob. 40PCh. 1 - Using data from appendix 8, construct a graph to...Ch. 1 - The sign convention for electron affinity can...Ch. 1 - Prob. 43PCh. 1 - 1.45 Figure 1.18 shows the emission spectrum of...
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- A photoemissive material has a threshold energy, Emin = 5 1019 J. Will 300. nm radiation eject electrons from the material? Explain.arrow_forward6.20 When light with a wavelength of 58.5 nm strikes the surface of tin metal, electrons are ejected with a maximum kinetic energy of 2.691018 J. What is the binding energy of these electrons to the metal?arrow_forwardA particular microwave oven delivers 750 watts. (A watt is a unit of power, which is the joules of energy delivered, or used, per second.) If the oven uses microwave radiation of wavelength 12.6 cm, how many photons of this radiation are required to heat 1.00 g of water 1.00C, assuming that all of the photons are absorbed?arrow_forward
- Light with a wavelength of 405 nm fell on a strontium surface, and electrons were ejected. If the speed of an ejected electron is 3.36 105 m/s, what energy was expended in removing the electron from the metal? Express the answer in joules (per electron) and in kilojoules per mole (of electrons).arrow_forwardWhen the Sojourner spacecraft landed on Mars in 1997, the planet was approximately 7.8 107 km from Earth. How long did it take for the television picture signal to reach Earth from Mars?arrow_forwardA hydrogen-like ion has a nucleus of charge +Ze and a single electron outside this nucleus. The energy levels of these ions are Z2RH/n2 (where Z = atomic number). Calculate the wavelength of the transition from n = 3 to n = 2 for He+, a hydrogen-like ion. In what region of the spectrum does this emission occur?arrow_forward
- Cobalt-60 is a radioactive isotope used in medicine for the treatment of certain cancers. It produces particles and rays, the latter having energies of 1.173 and 1.332 MeV. (1 MeV = 106 electron-volts and 1 eV = 1.6022 1019 J.) What are the wave-length and frequency of a -ray photon with an energy of 1.173 MeV?arrow_forwardAn atom emits yellow light when an electron makes the transition from the n = 5 to the n = 1 level. In separate experiments, suppose you bombarded the n = 1 level of this atom with red light, yellow light (obtained from the previous emission), and blue light. In which experiment or experiments would the electron be promoted to the n = 5 level?arrow_forwardUsing the Heisenberg uncertainty principle, calculate x for each of the following. a. an electron with v = 0.100 m/s b. a baseball (mass = 145 g) with v = 0.100 m/s How does the answer in part a compare with the size of a hydrogen atom? How does the answer in part b correspond to the size of a baseball?arrow_forward
- 6.85 The visible lines in the hydrogen atom emission spectrum arise from transitions with a final state with n = 2. In what spectral region should we expect to find transitions that have a final state of n = 1 ? Explain your reasoning using an energy level diagram similar to the one in Problem 6.26.arrow_forwardAn electron in a hydrogen atom in the level n = 5 undergoes a transition to level n = 3. What is the frequency of the emitted radiation?arrow_forwardThe most prominent line in the emission spectrum of chromium is found at 425.4 nm. Other lines in the chromium spectrum are found at 357.9 nm, 359.3 nm, 360.5 nm, 427.5 nm, 429.0 nm, and 520.8 nm. (a) Which of these lines represents the most energetic light? (b) What color is light of wavelength 425.4 nm?arrow_forward
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