Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 10, Problem 59P
When heated with H2SO4, both 3,3-dimethyl-2-butanol and 2,3·dimethyl-2-butnnol are dehydrated to form 2,3-dimethyl-2-butene. Which alcohol dehydrates more rapidly?
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When heated with H2SO4, both 3,3-dimethyl-2-butanol and 2,3-dimethyl-2-butanol are dehydrated to form 2,3-dimethyl-2-butene. Which alcohol dehydrates more rapidly?
1. O-hydroxybenzoic acid is a major product formed with phenol and which other reactant/s
I-primary alcohol
II-sodium hydroxide
III-water
IV-carbon dioxide
A.I and III
B. I and IV
C. II and III
D. II and IV
Rank the alcohols in order of increasing reactivity when dehydrated with H2SO4.
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- Show how to prepare each compound from 2-methyl- 1- propanol. a. 2- methylpropene b. 2- methyl- 2- propanol c. 2- methylpropanoic acid (CH3)2CHCOOHarrow_forwardI need to rank the alcohols in order of increasing reactivity when dehydrated with H2SO4arrow_forwardShow how each alcohol or diol can be prepared from an alkene. (a) 2-Pentanol (b) 1-Pentanol (c) 2-Methyl-2-pentanol (d) 2-Methyl-2-butanol (e) 3-Pentanol (f) 3-Ethyl-3-pentanol (g) 1,2-Hexanediolarrow_forward
- 1. (a) Which compound would have the highest boiling point? benzophenone toluene acetophenone benzaldehyde (b) Which of the reagents listed below can convert a primary alcohol to an aldehyde? H2CrO4 DMSO, (COCl)2, Et3N AgNO3 KMnO4-, NaOH (c) Oxidation of alcohols involving the use of DMSO and (COCl)2 is also known as which of the following? Jones Tollens Baeyer-Villiger Swernarrow_forwardwhich compound has the highest boiling point: hexan-1-ol or 3,3-dimethylbutan-1-ol?arrow_forward1. Which compound is more soulable in water : CH3 CH2 CH2 CH2 CH2 CH3 OR CH3 CH2 CH2 CH2 COOH 2. Which compound is more soulable in organic solvent : CH3 CH2 CH2 CH2 CH2 CH3 OR CH3 CH2 CH2 CH2 COOHarrow_forward
- 6. Show how to prepare each compound from 2-methyl-1-propanol. (a) 2-Methylpropene (b) 2-Methyl-2-propanol (c) 2-Methylpropanoic acidarrow_forward(iii ) Using benzoyl chloride (C_(6)H_(5)COCl ) General Reaction:arrow_forwardDraw the product formed when the alcohol cyclobutanol is dehydrated with H2SO4.arrow_forward
- Which alcohol below has the lowest acidity * a) methanol b) Ethanol c) Isopropanol d) Tert-butanol e) ndaarrow_forwardOf the following reagents, which could be used to make the alcohol shown? 1. H2O/H30+ 2. 1) Hg(OAc)2 H2O:2) NaBH4 3. ) 1) BH3;2)H2O2, OH-arrow_forwardWhen heated with H2SO4, both 3,3-dimethyl-2-butanol and 2,3-dimethyl-2-butanol are dehydrated to form 2,3-dimethyl-2-butene. Which alcoholdehydrates more rapidly?arrow_forward
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