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ChemistryChemistry9th Edition

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Chapter 14, Problem 101E
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Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097

Solutions

Chapter
Section
Problem 1RQ
Problem 2RQ
Problem 3RQ
Problem 4RQ
Problem 5RQ
Problem 6RQ
Problem 7RQ
Problem 8RQ
Problem 9RQ
Problem 10RQ
Problem 1ALQ
Problem 2ALQ
Problem 3ALQ
Problem 4ALQ
Problem 5ALQ
Problem 6ALQ
Problem 7ALQ
Problem 8ALQ
Problem 9ALQ
Problem 10ALQ
Problem 11ALQ
Problem 12ALQ
Problem 13ALQ
Problem 14ALQ
Problem 15ALQ
Problem 16ALQ
Problem 17ALQ
Problem 18ALQ
Problem 19Q
Problem 20Q
Problem 21Q
Problem 22Q
Problem 23Q
Problem 24Q
Problem 25Q
Problem 26Q
Problem 27Q
Problem 28Q
Problem 29Q
Problem 30Q
Problem 31Q
Problem 32Q
Problem 33Q
Problem 34Q
Problem 35E
Problem 36E
Problem 37E
Problem 38E
Problem 39E
Problem 40E
Problem 41E
Problem 42E
Problem 43E
Problem 44E
Problem 45E
Problem 46E
Problem 47E
Problem 48E
Problem 49E
Problem 50E
Problem 51E
Problem 52E
Problem 53E
Problem 54E
Problem 55E
Problem 56E
Problem 57E
Problem 58E
Problem 59E
Problem 60E
Problem 61E
Problem 62E
Problem 63E
Problem 64E
Problem 65E
Problem 67E
Problem 68E
Problem 69E
Problem 70E
Problem 72E
Problem 73E
Problem 74E
Problem 75E
Problem 76E
Problem 77E
Problem 78E
Problem 79E
Problem 80E
Problem 81E
Problem 82E
Problem 83E
Problem 84E
Problem 85E
Problem 86E
Problem 87E
Problem 88E
Problem 89E
Problem 90E
Problem 91E
Problem 92E
Problem 93E
Problem 94E
Problem 95E
Problem 96E
Problem 97E
Problem 99E
Problem 100E
Problem 101E
Problem 102E
Problem 103E
Problem 104E
Problem 105E
Problem 106E
Problem 107E
Problem 108E
Problem 109E
Problem 110E
Problem 111E
Problem 112E
Problem 113E
Problem 114E
Problem 115E
Problem 116E
Problem 117E
Problem 118E
Problem 119E
Problem 120E
Problem 121E
Problem 122E
Problem 123E
Problem 124E
Problem 125E
Problem 126E
Problem 127E
Problem 128E
Problem 129E
Problem 130E
Problem 131E
Problem 132E
Problem 133E
Problem 134E
Problem 135E
Problem 136E
Problem 137E
Problem 138E
Problem 139E
Problem 140E
Problem 141E
Problem 142E
Problem 143AE
Problem 144AE
Problem 145AE
Problem 146AE
Problem 147AE
Problem 148AE
Problem 149AE
Problem 150AE
Problem 151AE
Problem 152AE
Problem 153AE
Problem 154AE
Problem 155AE
Problem 156AE
Problem 157AE
Problem 158AE
Problem 159AE
Problem 160AE
Problem 161AE
Problem 162CWP
Problem 163CWP
Problem 164CWP
Problem 165CWP
Problem 166CWP
Problem 167CWP
Problem 168CWP
Problem 169CWP
Problem 170CP
Problem 171CP
Problem 172CP
Problem 173CP
Problem 174CP
Problem 175CP
Problem 176CP
Problem 177CP
Problem 178CP
Problem 179CP
Problem 180CP
Problem 181CP
Problem 182CP
Problem 183CP
Problem 184CP
Problem 185CP
Problem 186CP
Problem 187IP
Problem 188IP
Problem 189IP
Problem 190MP
Problem 191MP
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Chemistry

9th Edition
Steven S. Zumdahl
ISBN: 9781133611097
Textbook Problem

What is the percent ionization in each of the following solutions?

a. 0.10 M NH3

b. 0.010 M NH3

c. 0.10 M CH3NH2

(a)

Interpretation Introduction

Interpretation: The percent ionization in each of the given solutions is to be calculated.

Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution.

The pH of a solution is calculated by the formula, pH=−log[H+]

At equilibrium, the equilibrium constant expression is expressed by the formula,

Kb=Concentration of productsConcentration of reactants

The percent ionization of an acid is calculated by the formula,

Percent ionization=Equilibrium concentration of [OH−]Initial concentration of the base×100

Explanation

Explanation

The equilibrium constant expression for the stated ionization reaction is,

Kb=[NH4+][OH−][NH3]

NH3 is a weaker base.

The dominant equilibrium reaction for the given case is,

NH3(aq)+H2O(l)⇌NH4+(aq)+OH−(aq)

At equilibrium, the equilibrium constant expression is expressed by the formula,

Kb=Concentration of productsConcentration of reactants

Where,

  • Kb is the base ionization constant.

The equilibrium constant expression for the given reaction is,

Kb=[NH4+][OH−][NH3] (1)

The [OH−] is 1.34×10-3 M_ .

The change in concentration of NH3 is assumed to be x .

The liquid components do not affect the value of the rate constant.

The ICE table for the stated reaction is,

NH3(aq)⇌NH4+(aq)+OH−(aq)Inititial concentration0.1000Change−x+x+xEquilibrium concentration0.10−xxx

The equilibrium concentration of [NH3] is (0.10−x) M .

The equilibrium concentration of [NH4+] is x M .

The equilibrium concentration of [OH−] is x M .

The Kb value is 1.8×10−5

(b)

Interpretation Introduction

Interpretation: The percent ionization in each of the given solutions is to be calculated.

Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution.

The pH of a solution is calculated by the formula, pH=−log[H+]

At equilibrium, the equilibrium constant expression is expressed by the formula,

Kb=Concentration of productsConcentration of reactants

The percent ionization of an acid is calculated by the formula,

Percent ionization=Equilibrium concentration of [OH−]Initial concentration of the base×100

(c)

Interpretation Introduction

Interpretation: The percent ionization in each of the given solutions is to be calculated.

Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution.

The pH of a solution is calculated by the formula, pH=−log[H+]

At equilibrium, the equilibrium constant expression is expressed by the formula,

Kb=Concentration of productsConcentration of reactants

The percent ionization of an acid is calculated by the formula,

Percent ionization=Equilibrium concentration of [OH−]Initial concentration of the base×100

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Ch-14 P-1RQCh-14 P-2RQCh-14 P-3RQCh-14 P-4RQCh-14 P-5RQCh-14 P-6RQCh-14 P-7RQCh-14 P-8RQCh-14 P-9RQCh-14 P-10RQ
Ch-14 P-1ALQCh-14 P-2ALQCh-14 P-3ALQCh-14 P-4ALQCh-14 P-5ALQCh-14 P-6ALQCh-14 P-7ALQCh-14 P-8ALQCh-14 P-9ALQCh-14 P-10ALQCh-14 P-11ALQCh-14 P-12ALQCh-14 P-13ALQCh-14 P-14ALQCh-14 P-15ALQCh-14 P-16ALQCh-14 P-17ALQCh-14 P-18ALQCh-14 P-19QCh-14 P-20QCh-14 P-21QCh-14 P-22QCh-14 P-23QCh-14 P-24QCh-14 P-25QCh-14 P-26QCh-14 P-27QCh-14 P-28QCh-14 P-29QCh-14 P-30QCh-14 P-31QCh-14 P-32QCh-14 P-33QCh-14 P-34QCh-14 P-35ECh-14 P-36ECh-14 P-37ECh-14 P-38ECh-14 P-39ECh-14 P-40ECh-14 P-41ECh-14 P-42ECh-14 P-43ECh-14 P-44ECh-14 P-45ECh-14 P-46ECh-14 P-47ECh-14 P-48ECh-14 P-49ECh-14 P-50ECh-14 P-51ECh-14 P-52ECh-14 P-53ECh-14 P-54ECh-14 P-55ECh-14 P-56ECh-14 P-57ECh-14 P-58ECh-14 P-59ECh-14 P-60ECh-14 P-61ECh-14 P-62ECh-14 P-63ECh-14 P-64ECh-14 P-65ECh-14 P-67ECh-14 P-68ECh-14 P-69ECh-14 P-70ECh-14 P-72ECh-14 P-73ECh-14 P-74ECh-14 P-75ECh-14 P-76ECh-14 P-77ECh-14 P-78ECh-14 P-79ECh-14 P-80ECh-14 P-81ECh-14 P-82ECh-14 P-83ECh-14 P-84ECh-14 P-85ECh-14 P-86ECh-14 P-87ECh-14 P-88ECh-14 P-89ECh-14 P-90ECh-14 P-91ECh-14 P-92ECh-14 P-93ECh-14 P-94ECh-14 P-95ECh-14 P-96ECh-14 P-97ECh-14 P-99ECh-14 P-100ECh-14 P-101ECh-14 P-102ECh-14 P-103ECh-14 P-104ECh-14 P-105ECh-14 P-106ECh-14 P-107ECh-14 P-108ECh-14 P-109ECh-14 P-110ECh-14 P-111ECh-14 P-112ECh-14 P-113ECh-14 P-114ECh-14 P-115ECh-14 P-116ECh-14 P-117ECh-14 P-118ECh-14 P-119ECh-14 P-120ECh-14 P-121ECh-14 P-122ECh-14 P-123ECh-14 P-124ECh-14 P-125ECh-14 P-126ECh-14 P-127ECh-14 P-128ECh-14 P-129ECh-14 P-130ECh-14 P-131ECh-14 P-132ECh-14 P-133ECh-14 P-134ECh-14 P-135ECh-14 P-136ECh-14 P-137ECh-14 P-138ECh-14 P-139ECh-14 P-140ECh-14 P-141ECh-14 P-142ECh-14 P-143AECh-14 P-144AECh-14 P-145AECh-14 P-146AECh-14 P-147AECh-14 P-148AECh-14 P-149AECh-14 P-150AECh-14 P-151AECh-14 P-152AECh-14 P-153AECh-14 P-154AECh-14 P-155AECh-14 P-156AECh-14 P-157AECh-14 P-158AECh-14 P-159AECh-14 P-160AECh-14 P-161AECh-14 P-162CWPCh-14 P-163CWPCh-14 P-164CWPCh-14 P-165CWPCh-14 P-166CWPCh-14 P-167CWPCh-14 P-168CWPCh-14 P-169CWPCh-14 P-170CPCh-14 P-171CPCh-14 P-172CPCh-14 P-173CPCh-14 P-174CPCh-14 P-175CPCh-14 P-176CPCh-14 P-177CPCh-14 P-178CPCh-14 P-179CPCh-14 P-180CPCh-14 P-181CPCh-14 P-182CPCh-14 P-183CPCh-14 P-184CPCh-14 P-185CPCh-14 P-186CPCh-14 P-187IPCh-14 P-188IPCh-14 P-189IPCh-14 P-190MPCh-14 P-191MP

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