CHEMISTRY:CENTRAL SCIENCE-W/MOD.ACCESS
CHEMISTRY:CENTRAL SCIENCE-W/MOD.ACCESS
14th Edition
ISBN: 9780134809694
Author: Brown
Publisher: PEARSON
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Chapter 14.6, Problem 14.13.2PE

Practice Exercise 2
Consider the following reaction: 2NO(g) + Br2(g) → 2 NOBr(g).

  1. Write the rate law for the reaction, assuming it involves a sigle elementary reaction.
  2. Is a single-step mechanism likely for this reaction?

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For the given equation at 600 oC:​CO(g) + Cl2(g) à COCl2(g), the following data were collected: ​ ​​Experiment​[CO] (M)​[Cl2] (M)​Rate of appearance COCl2 (M/s) ​ 1​​ 0.24​​ 0.40​​​0.121 ​​ 2​​ 0.48​ ​ 0.40​​​0.241 ​​ 3​​ 0.24​​ 0.80​​​0.483 Determine the Rate Law and the value of the Rate constant (with appropriate units).
Chlorine dioxide reacts in basic water to form chlorite and chlorate according to the following chemical equation:       2ClO2(aq)   +     2OH–(aq)    →    ClO2–(aq)    +     ClO3–(aq)    +      H2O A kinetic study of this reaction under a certain set of conditions yielded the data below. Experiment [ClO2] (M) [OH-] (M) Rate (M/s) 1 0.0500 0.100 5.75 x 10-2 2 0.100 0.100 2.30 x 10-1 3 0.100 0.0500 1.15 x 10-1 What is the rate law?
Consider the following reaction and the experimental data in the table below.2 ??(?) + ?2(?) → 2 ??2(?)Experiment [NO] (M) [O2] (M) Initial Rate (M/s)       1               0.10         0.10             0.18       2               0.10         0.20             0.35       3               0.20         0.20             1.42Calculate the rate of the reaction when [NO] = 0.35 M and [O2] = 0.65 M
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