Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Explain the relevance pi* (antibonding) -molecular orbitals have in nucleophilic addition reactions of carbonyl containing compounds.
What reaction converts benzoic acid to m-bromobenzoic acid?
Alkylation
Acylation
Halogenation
Hydrohalogenation
Hydration
Reduction
Oxidation
Nitration
Sulfonation
Can pyridine form a diazonium salt and can quinoline and isoquinoline undergo electrophilic substitution on the benzenoid ring but nucleophilic substitution on the nitrogen ring?
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- Thioglycolic acid, HSCH2CO2H, a substance used in depilatory agents (hair removers) has pKa = 3.42. What is the percent dissociation of thioglycolic acid in a buffer solution at pH = 3.0?arrow_forwardIdentify the best reagents to complete the following reaction. HO, CIarrow_forwardWhat is the source of the nucleophilic attack? How does the oxygen get protonated? What causes the elimination reaction?arrow_forward
- Benzene + nitration, followed by bromination, then reduction of the nitro group to an amine, followed by diazonization, addition of copper I cyanide to the reaction and the product is O benzoyl nitrile O ortho-bromoaniline O para-bromo-nitrobenzene O 3,5-dibromnobenzonitrile O para-bromobenzyl bromidearrow_forwardPredict the products formed when cyclohexanone reacts with the following reagents. h) sodium acetylide, then mild H3O+arrow_forwardRank the following carbonyl compounds in order of increasing reactivity in nucleophilic substitution reactions: H I II III IV ZIarrow_forward
- The synthesis of acetanilide from aniline and acetic anhydride follows which mechanism? Electrophilic Aromatic Substitution Nucleophilic Substitution Bimolecular Nucleophilic Acyl Substitution Nucleophilic Substitution Unimoleculararrow_forwardThe product of reaction between formaldehyde with 2-methyl propanal give 2,2-dimethyl-3-hydroxy propanal 2,2-dimethyl-3-hydroxy propanone 2,2-dimethyl-3-hydroxy propanoic acid 2,2-dimethyl-3-hydroxy propanol 4-phenyl-3-buten-2-one prepared from reaction between Benzaldehyde with acetic acid Benzaldehyde with acetaldehyde Benzaldehyde with formaldehyde Benzaldehyde with acetone Which predict product for reaction between heptane-6-one-1-al with sodium hydroxide * 1-(2-hydroxycyclopentyl) pentanone 1-(2-hydroxycyclopentyl) butanone 1-(2-hydroxycyclopentyl) ethanone 1-(2-hydroxycyclopentyl) propanonearrow_forwardIn the reaction of acetone with sodium borohydride, what is the geometry of the reaction intermediate that results from the nucleophilic addition of the hydride ion to the carbonyl group? A) trigonal planar B) tetrahedral C) linear D) octahedralarrow_forward
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