Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
Fundamentals of Chemical Engineering Thermodynamics (MindTap Course List)
1st Edition
ISBN: 9781111580704
Author: Kevin D. Dahm, Donald P. Visco
Publisher: Cengage Learning
Question
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Chapter 4.8, Problem 28P

(A)

Interpretation Introduction

Interpretation:

To determine the mass of steam.

Concept Introduction:

The mass of steam using the relation specific volume and volume.

m=VV^

Here, specific volume is V^ and volume is V.

(B)

Interpretation Introduction

Interpretation:

To determine the volume of the chamber that was initially evacuated.

Concept Introduction:

The steady state energy balance equation for the chambers.

ddt{M(U^+v22+gh)}=(j=1j=Jm˙j,in(H^j+vj22+ghj)k=1k=Km˙k,out(H^k+vk22+ghk)+W˙S+W˙EC+Q˙)

Here, time taken is t, total mass of the system is M, specific internal energy of the system is U^, velocity of the system is v, height of the system is h, acceleration due to gravity is g, mass flow rate for inlet and outlet streams is m˙j,in and m˙k,out, specific enthalpies of streams inlet and outlet is H^j and H^k, heights at which streams enters and leave the system is hj and hk, rate at which work is added to the system through expansion or contraction of the system is W˙EC, rate at which shaft work is added to the system is W˙S, and the rate at which heat is added to the system is Q˙.

(C)

Interpretation Introduction

Interpretation:

To determine the change in entropy of the universe.

Concept Introduction:

The general expression for an entropy balance equation.

d(MS^)dt=j=1j=Jm˙j,inS^jk=1k=Km˙k,outS^k+n=1n=NQ˙nTn+S˙gen

Here, time taken is t, mass of the system is M, specific entropy of the system is S^, mass flow rates of individual streams entering and leaving the system are m˙j,in and m˙k,out, specific entropies of streams entering and leaving the system are S^j and S^k, actual rate at which heat is added to or removed from the system at one particular location is Q˙n, the temperature of the system at the boundary where the heat transfer labeled n occurs is Tn, and the rate at which entropy is generated within the boundaries of the system is S˙gen.

(D)

Interpretation Introduction

Interpretation:

Determine the value entropy generation.

Concept Introduction:

Write the number of moles using the ideal gas law.

n=PVRT

Here, pressure is P, volume is V, gas constant is R, and temperature is T.

Write the entropy difference between the two chambers.

S_2S_1=CV*ln(T2T1)+Rln(T2P1T1P2)=(CP*R)ln(T2T1)+Rln(T2P1T1P2)

Here, initial and final pressure and temperature is P1,P2,T1,andT2, gas constant is R, constant pressure heat capacity on a gas basis is CP*.

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