Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Question
Chapter 6, Problem 6.132EP

(a)

Interpretation Introduction

Interpretation:

The organic product formed in the given reaction has to be indicated as primary amide, secondary amide, tertiary amide, or not an amide.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(a)

Expert Solution
Check Mark

Answer to Problem 6.132EP

Organic product obtained is a primary amide.

Explanation of Solution

Given reaction is,

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  1

In amidification process, OH from carboxylic acid and H from amine or ammonia is lost to form amide as product.  Looking into the given reaction, it is found that a carboxylic acid and ammonia is present as reactant and the reaction is conducted at high temperature.  The product obtained is a primary amide.  This is an amidification reaction.

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  2

Conclusion

The product obtained is indicated.

(b)

Interpretation Introduction

Interpretation:

The organic product formed in the given reaction has to be indicated as primary amide, secondary amide, tertiary amide, or not an amide.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(b)

Expert Solution
Check Mark

Answer to Problem 6.132EP

Organic product obtained is a secondary amide.

Explanation of Solution

Given reaction is,

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  3

In amidification process, OH from carboxylic acid and H from amine or ammonia is lost to form amide as product.  Looking into the given reaction, it is found that a carboxylic acid and primary amine is present as reactant and the reaction is conducted at high temperature.  The product obtained is a secondary amide.  This is an amidification reaction.

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  4

Conclusion

The product obtained is indicated.

(c)

Interpretation Introduction

Interpretation:

The organic product formed in the given reaction has to be indicated as primary amide, secondary amide, tertiary amide, or not an amide.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(c)

Expert Solution
Check Mark

Answer to Problem 6.132EP

Organic product obtained is a tertiary amide.

Explanation of Solution

Given reaction is,

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  5

In amidification process, OH from carboxylic acid and H from amine or ammonia is lost to form amide as product.  Looking into the given reaction, it is found that a carboxylic acid and secondary amine is present as reactant and the reaction is conducted at high temperature.  The product obtained is a tertiary amide.  This is an amidification reaction.

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  6

Conclusion

The product obtained is indicated.

(d)

Interpretation Introduction

Interpretation:

The organic product formed in the given reaction has to be indicated as primary amide, secondary amide, tertiary amide, or not an amide.

Concept Introduction:

Amides are synthesized using amidification reaction.  This involves a reaction between amine and carboxylic acid.  In this reaction, the OH group present in carboxylic acid and H from ammonia or amine is lost to give amide as the product.  Water is obtained as a by-product in this reaction.  The general reaction scheme for synthesis of amides can be given as,

Ammonia + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amideamine + Carboxylic acid 100 °C amide

(d)

Expert Solution
Check Mark

Answer to Problem 6.132EP

Organic product obtained is a tertiary amide.

Explanation of Solution

Given reaction is,

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  7

In amidification process, OH from carboxylic acid and H from amine or ammonia is lost to form amide as product.  Looking into the given reaction, it is found that a carboxylic acid and secondary amine is present as reactant and the reaction is conducted at high temperature.  The product obtained is a tertiary amide.  This is an amidification reaction.

Organic And Biological Chemistry, Chapter 6, Problem 6.132EP , additional homework tip  8

Conclusion

The product obtained is indicated.

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Chapter 6 Solutions

Organic And Biological Chemistry

Ch. 6.4 - Prob. 1QQCh. 6.4 - Prob. 2QQCh. 6.5 - Prob. 1QQCh. 6.5 - Prob. 2QQCh. 6.5 - Prob. 3QQCh. 6.6 - Prob. 1QQCh. 6.6 - Prob. 2QQCh. 6.6 - Prob. 3QQCh. 6.7 - Prob. 1QQCh. 6.7 - Prob. 2QQCh. 6.7 - Prob. 3QQCh. 6.8 - Prob. 1QQCh. 6.8 - Prob. 2QQCh. 6.8 - Prob. 3QQCh. 6.8 - Prob. 4QQCh. 6.9 - Prob. 1QQCh. 6.9 - Prob. 2QQCh. 6.10 - Prob. 1QQCh. 6.10 - Prob. 2QQCh. 6.10 - Prob. 3QQCh. 6.10 - Prob. 4QQCh. 6.11 - Prob. 1QQCh. 6.11 - Prob. 2QQCh. 6.11 - Prob. 3QQCh. 6.12 - Prob. 1QQCh. 6.12 - Prob. 2QQCh. 6.12 - Prob. 3QQCh. 6.12 - Prob. 4QQCh. 6.13 - Prob. 1QQCh. 6.13 - Prob. 2QQCh. 6.13 - Prob. 3QQCh. 6.13 - Prob. 4QQCh. 6.14 - Prob. 1QQCh. 6.14 - Prob. 2QQCh. 6.14 - Prob. 3QQCh. 6.15 - Prob. 1QQCh. 6.15 - Prob. 2QQCh. 6.16 - Prob. 1QQCh. 6.16 - Prob. 2QQCh. 6.16 - Prob. 3QQCh. 6.17 - Prob. 1QQCh. 6.17 - Prob. 2QQCh. 6.17 - Prob. 3QQCh. 6.18 - Prob. 1QQCh. 6.18 - Prob. 2QQCh. 6.18 - Prob. 3QQCh. 6.19 - Prob. 1QQCh. 6.19 - Prob. 2QQCh. 6.19 - Prob. 3QQCh. 6.19 - Prob. 4QQCh. 6 - Prob. 6.1EPCh. 6 - Prob. 6.2EPCh. 6 - Prob. 6.3EPCh. 6 - Prob. 6.4EPCh. 6 - Prob. 6.5EPCh. 6 - Prob. 6.6EPCh. 6 - Prob. 6.7EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Indicate whether each of the compounds in Problem...Ch. 6 - Prob. 6.10EPCh. 6 - Prob. 6.11EPCh. 6 - Prob. 6.12EPCh. 6 - Prob. 6.13EPCh. 6 - Prob. 6.14EPCh. 6 - Prob. 6.15EPCh. 6 - Prob. 6.16EPCh. 6 - Prob. 6.17EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.19EPCh. 6 - Prob. 6.20EPCh. 6 - Prob. 6.21EPCh. 6 - Prob. 6.22EPCh. 6 - Prob. 6.23EPCh. 6 - Prob. 6.24EPCh. 6 - Prob. 6.25EPCh. 6 - Classify each of the following compounds as a 1...Ch. 6 - Prob. 6.27EPCh. 6 - Prob. 6.28EPCh. 6 - Prob. 6.29EPCh. 6 - Prob. 6.30EPCh. 6 - Prob. 6.31EPCh. 6 - Prob. 6.32EPCh. 6 - Prob. 6.33EPCh. 6 - Prob. 6.34EPCh. 6 - Determine the maximum number of hydrogen bonds...Ch. 6 - Prob. 6.36EPCh. 6 - Although they have similar molecular masses (73...Ch. 6 - Prob. 6.38EPCh. 6 - Prob. 6.39EPCh. 6 - Prob. 6.40EPCh. 6 - Show the structures of the missing substance(s) in...Ch. 6 - Prob. 6.42EPCh. 6 - Prob. 6.43EPCh. 6 - Prob. 6.44EPCh. 6 - Prob. 6.45EPCh. 6 - Prob. 6.46EPCh. 6 - Prob. 6.47EPCh. 6 - Prob. 6.48EPCh. 6 - Prob. 6.49EPCh. 6 - Prob. 6.50EPCh. 6 - Prob. 6.51EPCh. 6 - Prob. 6.52EPCh. 6 - Prob. 6.53EPCh. 6 - Prob. 6.54EPCh. 6 - Prob. 6.55EPCh. 6 - Prob. 6.56EPCh. 6 - Prob. 6.57EPCh. 6 - Prob. 6.58EPCh. 6 - Prob. 6.59EPCh. 6 - Prob. 6.60EPCh. 6 - Prob. 6.61EPCh. 6 - Prob. 6.62EPCh. 6 - Prob. 6.63EPCh. 6 - Prob. 6.64EPCh. 6 - Prob. 6.65EPCh. 6 - Prob. 6.66EPCh. 6 - Prob. 6.67EPCh. 6 - Prob. 6.68EPCh. 6 - Prob. 6.69EPCh. 6 - Prob. 6.70EPCh. 6 - Prob. 6.71EPCh. 6 - Prob. 6.72EPCh. 6 - Prob. 6.73EPCh. 6 - Prob. 6.74EPCh. 6 - Name each of the salts in Problem 17-71. a....Ch. 6 - Prob. 6.76EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.78EPCh. 6 - Prob. 6.79EPCh. 6 - Prob. 6.80EPCh. 6 - Prob. 6.81EPCh. 6 - Prob. 6.82EPCh. 6 - Prob. 6.83EPCh. 6 - Prob. 6.84EPCh. 6 - Prob. 6.85EPCh. 6 - Prob. 6.86EPCh. 6 - Prob. 6.87EPCh. 6 - Prob. 6.88EPCh. 6 - Prob. 6.89EPCh. 6 - Prob. 6.90EPCh. 6 - Prob. 6.91EPCh. 6 - Indicate whether each of the following statements...Ch. 6 - Prob. 6.93EPCh. 6 - Prob. 6.94EPCh. 6 - Prob. 6.95EPCh. 6 - Prob. 6.96EPCh. 6 - Prob. 6.97EPCh. 6 - Prob. 6.98EPCh. 6 - Indicate whether or not each of the following...Ch. 6 - Prob. 6.100EPCh. 6 - Classify each of the following amides as...Ch. 6 - Classify each of the following amides as...Ch. 6 - Prob. 6.103EPCh. 6 - Prob. 6.104EPCh. 6 - Prob. 6.105EPCh. 6 - Prob. 6.106EPCh. 6 - Prob. 6.107EPCh. 6 - Assign an IUPAC name to each of the following...Ch. 6 - Prob. 6.109EPCh. 6 - Prob. 6.110EPCh. 6 - Prob. 6.111EPCh. 6 - Prob. 6.112EPCh. 6 - Prob. 6.113EPCh. 6 - Prob. 6.114EPCh. 6 - Prob. 6.115EPCh. 6 - Prob. 6.116EPCh. 6 - Prob. 6.117EPCh. 6 - Prob. 6.118EPCh. 6 - Prob. 6.119EPCh. 6 - Prob. 6.120EPCh. 6 - Prob. 6.121EPCh. 6 - Prob. 6.122EPCh. 6 - Prob. 6.123EPCh. 6 - Prob. 6.124EPCh. 6 - Prob. 6.125EPCh. 6 - Prob. 6.126EPCh. 6 - Prob. 6.127EPCh. 6 - Prob. 6.128EPCh. 6 - Prob. 6.129EPCh. 6 - Prob. 6.130EPCh. 6 - Prob. 6.131EPCh. 6 - Prob. 6.132EPCh. 6 - Prob. 6.133EPCh. 6 - Prob. 6.134EPCh. 6 - Prob. 6.135EPCh. 6 - Prob. 6.136EPCh. 6 - Prob. 6.137EPCh. 6 - Prob. 6.138EPCh. 6 - Prob. 6.139EPCh. 6 - Prob. 6.140EPCh. 6 - Prob. 6.141EPCh. 6 - Prob. 6.142EPCh. 6 - Prob. 6.143EPCh. 6 - Prob. 6.144EPCh. 6 - Prob. 6.145EPCh. 6 - Draw the structure of the nitrogen-containing...Ch. 6 - Prob. 6.147EPCh. 6 - Prob. 6.148EPCh. 6 - Prob. 6.149EPCh. 6 - Prob. 6.150EPCh. 6 - Prob. 6.151EPCh. 6 - Prob. 6.152EPCh. 6 - Prob. 6.153EPCh. 6 - Prob. 6.154EP
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