CHM 206 Expt 12

An organic chemistry experiment involves a nucleophilic substitution (SN2) reaction using 1-iodobutane and 2-naphthoxide ion. The 2-naphthoxide ion is generated from 2-naphthol and sodium hydroxide in an ethanol solvent. The experiment includes steps like generating the nucleophile, conducting the SN2 reaction, and analyzing the product using 1H NMR spectroscopy. Question: Write the structure of the undesired side product if CH3CH2O‾ (ethoxide) reacts with 1-iodobutane.

Nucleophilic substitution reactions of Alkyl Halides experiment  1: In SN2 experiment with 12% sodium iodide in acetone react with  0.1ml alkyl halides 1-chlorobutane, 2-chlorobutane, Allyl chloride, 2-chloro-2-methylpropane, 1-chloro-2-methylpropane, 2-bromobutane what will be reactivity from being most reactive to least reactive. 2:  In SN1 experiment with 1% silver in ethanol react with  0.1ml alkyl halides 1-chlorobutane, 2-chlorobutane, Allyl chloride, 2-chloro-2-methylpropane, 1-chloro-2-methylpropane, 2-bromobutane what will be reactivity from being most reactive to least reactive.

Provide a mechanism for the following reaction. Provide a Mechanism.

organic chemistry 19) The sequence of reactions which gives benzoic acid from bromobenzene are

This is an organic chemistry question. PLEASE SHOW STEP BY STEP! ALSO PLEASE INCLUDE ALL ELECTRON LONE PAIRS AND CHARGES FOR STRUCTURES IF NECESSARY! Make sure you include a detailed explanation of your answer.

In the presence of excess base and excess halogen, a methyl ketone is converted to a carboxylate ion. The reaction is known as the haloform reaction because one of the products is haloform (chloroform, bromoform, or iodoform). Before spectroscopy became a routine analytical tool, the haloform reaction served as a test for methyl ketones: the formation of iodoform, a bright yellow compound, signaled that a methyl ketone was present. Why do only methyl ketones form a haloform?

In the presence of excess base and excess halogen, a methyl ketone is converted to a carboxylate ion. The reaction is known as the haloform reaction because one of the products is haloform (chloroform, bromoform, or iodoform). Before spectroscopy became a routine analytical tool, the haloform reaction served as a test for methyl ketones: the formation of iodoform, a bright yellow compound, signaled that a methyl ketone was present. Why do only methyl ketones form a haloform?

Chemistry

b) Design a synthetic scheme using the reagents given for the following two reactions. All reagents are used for each reaction scheme and in each case, a reagent can be used more than once. Take the necessary time to complete this question. i) = 2 eq. ii) 2 eq. O O H₂/Lindlar's catalyst Br₂/CH₂Cl₂ Se joon NaH H₂O+/H₂O H H₂/Lindlar's catalyst PCC/CH₂Cl₂ NaH lan -H H3O+/H₂O CH₂Br

Acylation of Toluene please answer 4-7

show-all-working-explaining-detailly-each-step Answer should be typewritten with a computer keyboard.

Give answer both subparts ASAP Thanks

01:50 4G File Details 4CH003/UM1: Fundamentals of... Introduction NaBH4 OH C=0 H benzophenone diphenylmethanol Ketones are readily reduced to secondary alcohols by reaction with sodium borohydride. The aim of this experiment is to determine the time required to effect the complete conversion of the ketone, benzophenone to diphenylmethanol at room temperature. This investigation may be achieved by isolating and analyzing the reaction product after different reduction times. Infrared spectroscopy affords a convenient method of analysis; by comparing the IR spectrum of the crude reaction product at different time intervals one would expect to see the intensity of the hydroxyl absorption peak increase relative to that of the original carbonyl peak. From this you can deduce the optimum time for the reduction process at room temperature. Procedure Note the "reduction time" that the demonstrator assigns to your group. Different groups will be assigned different times, eithert = 2.5 minutes,…

h- Syl Nucleophilic substitution i- Sy2 Nucleophilic substitution j- Electrophilic aromatic substitution a - Proton transfer e - Electrophilic addition b- Lewis acid/base f-E1 Elimination c- Radical chain substitution d = Radical chain addition. g- E2 Elimination Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - j for your answers. HI AICI3 Cl- AICI, OEt Na OEt OEt HOET Na AIBN CN 70° poly(acrylonitrile) (Orlon, Acrilan)

5 a) For each of the reactions below, describe a suitable reaction mechanism, stating the reaction conditions and naming the major productsi) Nitrobenzene and Chloromethaneft) 2-chloro-2-methyl propane and aqueous potassium hydroxide.iii) Propanone and hydrogen cyanide.iv) iodoethane and sodium hydroxide in ethanol.b) i) Discuss the bonding and extra.stability of benzene,ii) Using suitable examples, compare the reactivity of benzene and ethane,

pluginfile.php/477064/modresource/content/0/Chem%20154%20Exam%202%20F2019%20Loudon%20ch%204.pdf ch 4.pdf 3/5 5.1 Mechanisms. Using curved arrows, suggest a reasonable mechanism for each indicated reaction. H3PO4 water, dilute a) b) H3PO4 HO. H20

Ethers/Aldehydes/Ketones Synthesis Prepare the following compounds from any simple alkyl halide having four carbons or less, cyclohexane, and/or benzene. You may also use ethylene oxide (oxacyclopropane). SHOW ALL STEPS AND REAGENTS. 1. 3. cof مل 2. он OCH2CH3 HO 4. 6. 7. 8. 9. 10. Sr

Step 4a: Classify step. The target product is present, but the reaction is not over. The ethoxide ion has been regenerated. :0: :0: What is the key process in the next step of the mechanism? proton transfer formation of a o bond between nucleophile and electrophile loss of a leaving group carbocation rearrangement (e.g., methyl or hydride shift)

MCQ 16: In SN2 mechanism 'S' stands for A. subordinate B. substitution C. sub-reaction D. systemic reaction

Please answer all parts asap

1. 2. OH a Proton transfer b = Lewis acid/base c = Electrophilic addition 1. CH3OH 2. H₂SO4 130⁰ OCH3 d e HCI H₂O E1 Elimination E2 Elimination The rections above involve synthesis or reactions of alcohols and ethers. Identify the mechanism by which they proceed from among the mechanisms listed. Use the letters a - g for your answers. f = SN1 Nucleophilic substitution g = SN2 Nucleophilic substitution

The following IR and NMR were obtained for Alicia’s Intermediate product, Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Label all hydrogens with the data from 1H NMR. Label all carbons with the provided data from 13C NMR.