152 practice final

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Washington University in St Louis *

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152

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Chemistry

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Feb 20, 2024

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1 Name (PRINT) _________________________________________ Student ID ______________________ Chem 152 FINAL EXAM This practice exam is the same as the final exam given in Spring 2021.
Name (PRINT) _________________________________________ Student ID ______________________ 2 1. (27 pts total) Shown below is the cooling curve for 0.7135 g of MgO of unknown purity reacting with a solution of excess HCl in a calorimeter (the impurities do not react with HCl). The overall heat capacity of the solution is 311.0 J/°C. 1.1 (8 pts) Assuming no loss of heat to the environment, calculate the total heat absorbed by the solution (Q solution , in kJ). Show all work and enter your answer with the correct sign convention and number of significant figures in the box provided. 1.2 (6 pts) Using the heat of reaction given below, calculate the mass of MgO in the unknown. Show all work and enter your answer with the correct number of significant figures in the box provided. MgO (s) + 2 H + (aq) Mg 2+ (aq) + H 2 O (l) Δ Hrxn = 436.8 kJ/mol kJ g
Name (PRINT) _________________________________________ Student ID ______________________ 3 1.3 (4 pts) What is the percent purity of the MgO sample? Show all work and enter your answer with the correct number of significant figures in the box provided. 1.4 (9 pts) A second trial of the experiment was performed using 1.5000 g of the MgO unknown instead of 0.7135 g. Assuming HCl was still the excess reagent and the new mass was factored into calculations, circle the correct words to complete the statements below. a. The change in temperature for the second trial would be ( greater than , less than , equal to ) that of the first trial. b. The amount of heat evolved in the second trial would be ( greater than , less than , equal to ) the heat evolved in the first trial. c. The percent purity calculated from the second trial would be ( greater than , less than , equal to ) the percent purity calculated from the first trial. 2. (32 pts total) To obtain the solubility product, Ksp, of Ba(OH) 2 , a student stirs an excess amount of solid barium hydroxide in water, filters away the un-dissolved solid, and titrates 10.00 mL of the filtrate (a saturated Ba(OH) 2 solution) with 0.1526 M HCl. The student performs 4 trials and the volumes of HCl used in titrations are 20.62 mL, 21.22 mL, 20.88 mL, and 20.55 mL (average volume = 20.82 mL). 2.1 (4 pts) Listed below are four acid-base indicators available in the lab and their pKa values. Circle the indicator that is most appropriate for this titration. a. Methyl orange (pKa = 3.8) b. Bromocresol green (pKa = 4.5) c. Brillant yellow (pKa = 7.2) d. Phenolphthalein (pKa = 9.0) 2.2 (6 pts) Calculate the average deviation of the titration volume. Report your answer as “average volume ± average deviation” using correct number of significant figures. % ( + ) mL
Name (PRINT) _________________________________________ Student ID ______________________ 4 2.3 (6 pts) The student suspects the titration volume “21.22 mL” is inaccurate. Using a Q- test with the table of 90% confidence rejection quotients below, determine whether the trial should be retained or discarded. Circle the correct answer below and show all supporting work. # of measurements 3 4 5 6 7 Q0.90 0.94 0.76 0.64 0.56 0.51 Circle the correct answer: The data point ’21.22 mL’ should be ( retained / discarded ). Supporting work: 2.4 (10 pts) Using the average titration volume of HCl given in the problem, calculate the Ksp of Ba(OH) 2 . Show your work and enter your answer in the box.
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