580368 Determining the Ksp of Calcium Hydroxide Q
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Determining the K
sp
of Calcium Hydroxide
Student Name: Hailey Adeel
Date: 10/14/20
1
Data
Activity 1
Data Table 1
Sample 1
Sample 2
Sample 3
Mass of Erlenmeyer
Flask
53.46
53.78
54.21
Mass of Erlenmeyer
Flask + Calcium
Hydroxide Solution
(lime water)
56.45
56.89
58.31
Mass of Calcium
Hydroxide Solution
2.99
3.11
4.10
Volume of Ca(OH)
2
Density = 1.000 g/mL
3
3
3
Concentration of HCl
(M)
0.1
0.1
0.1
Initial HCl Volume in
Syringe
10
10
10
Final HCl Volume in
Syringe
7.3
6.8
7.2
Volume of HCl
Delivered
2.7
3.2
2.8
Moles of HCl
Delivered
.27 x 10^-6
.32 x 10^-6
.28 x 10^6
Moles of OH
-
in
Sample
0.3 x 10^-2
0.3 x 10^-2
0.3 x 10^-2
Moles of Ca
2+
in
Sample
0.03 x 10^-2
0.03 x 10^-2
0.03 x 10^-2
© 2016 Carolina Biological Supply Company
2
Sample 1
Sample 2
Sample 3
Molar Solubility (M)
0.0141
0.0138
0.0141
Calculated K
sp
0.081 x 10^-8
0.096 x 10^-8
0.084 x 10^-8
Average Calculated
K
sp
0.087x10^-8
0.087x10^-8
0.087x10^-8
Activity 2
Data Table 2
Sample 1
Sample 2
Sample 3
Mass of Erlenmeyer
Flask
53.89
53.92
54.10
Mass of Erlenmeyer
Flask + Calcium
Hydroxide Solution
(lime water)
56.97
57.02
57.46
Mass of Calcium
Hydroxide Solution
3.08
4.02
3.36
Volume of Ca(OH)
2
Density = 1.000 g/mL
0.02
0.03
0.02
Concentration of HCl
(M)
0.1
0.1
0.1
Initial HCl volume in
Syringe
10
10
10
© 2016 Carolina Biological Supply Company
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The reaction A(g) + 2B(g) C(g) was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate Kc for this reaction.
Round off the answer to two significant digits.
Group of answer choices
0.060
5.1
17
19
25
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CHEMISTRY 1110L
LAB REPORT: REACTIONS OF COPPER (Part B)
1. Reaction 4:
a. Color of copper(II) sulfate
b. Water solubility of copper(II) sulfate
2. Reaction 5:
CuO + H₂SO4 →
CuSO4 +
Zn →>>
-
5. Percent recovery
(calculations)
3. Mass of copper metal recovered
4. Initial mass of copper (from Part A)
CuSO4 +
Cu +
ZnSO4 +
Zn + H₂SO4
a. Color of zinc metal (before reaction)
b. Color/appearance of copper metal (after reaction)
c. Color of solution before reaction
d. Color of solution after reaction
e. Color of hydrogen gas
ZnSO4
H₂O
blue Solid
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6. Initials of instructor or teaching assistant (TA) own
H₂
Name
• Loona Alg busi
Partner
Desk #
AR
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cem 5
5
Constants I P
Part A
The concentration of Br in a sample of seawater is 3.3 - 10 M. If a liter of seawater has a mass of 1.0 kg, the concentration of Br is ppm.
O 3.3
O 0.33
O 0.0033
O 26
O 0.026
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Based on your ICE table (Part 2) and the definition of Ka, set up the expression for Ka in
order to determine the unknown. Each reaction participant must be represented by one
tile. Do not combine terms.
Ка
=
= 3.2 × 10-9
RESET
[0]
[0.110]
[0.220]
[0.101]
[0.229]
[0.106]
☑
(x)]
[2x]
[0.110+x]
[0.110-x]
[0.220 + x]
[0.220-x]
[0.101 + x]
[0.101 - x]
[0.229 +x]
[0.229-x]
[0.106 + x]
[0.106 - x]
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2
3
Based on your ICE table (Part 2) and the equilibrium expression for Ka (Part 3),
determine the pH of solution.
pH =
RESET
0
20.3
2.03
8.85
5.15
1.41 × 10-*
7.09 × 10-€
0.110
0.958
1.96
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In(k) vs 1/T
-5
-50200315 0.002 0.00325 0.0033 0.00335 0.0034
-5.4 +
-5.6
y = -9253x + 24.504
25.8
-6
-6.2
-6.4
-6.6
-6.8
1/T
a) 24.504 Ea
b) -9253 = LnA
c) -9253 -Ea
d) -9253-Ea/R
=
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Determine the pH of a solution of aspirin (acetylsalicylic acid, HC,H7O4)
by constructing an ICE table, writing the equilibrium constant expression,
and using this information to determine the pH. The Ka of aspirin is 3.3 ×
104. Complete Parts 1-3 before submitting your answer.
1
2
3
NEXT
652 mg of aspirin (HC9H7O4) is dissolved in an aqueous solution of 237 mL aqueous
solution. Fill in the ICE table with the appropriate value for each involved species to
determine concentrations of all reactants and products.
HC9H7O4(aq)
+
H₂O(1)
Initial (M)
Change (M)
Equilibrium (M)
☐
0
=
H3O+(aq)
+
C9H7O4(aq)
2.75 x 10-3
3.62 × 10-3
1.53 x 10-5
15.3
0.0153
RESET
+x
-x
2.75 x 10-3 + x
2.75 x 10-3-X
3.62 x 10-3 + x
3.62 x 10-3-X
1.53 x 10-5 + X
1.53 x 10-5-x
15.3 + x
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Based on your ICE table (Part 2) and the definition of Ka, set up the expression for Ka in
order to determine the unknown. Each reaction participant must be represented by one
tile. Do not combine terms.
Ka =
2.9 × 10-8
RESET
[0]
(0.13]
[0.37]
(0.010]
[0.040]
[0.10]
[0.40]
[x]
[2x]
[0.13 + x)
[0.13-x]
[0.010+x]
[0.010-x]
[0.040 + x] [0.040 - x]
[0.10+x]
[0.10-x]
[0.40+x]
[0.40-x]
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2
Based on your ICE table (Part 2) and the equilibrium expression for Ka (Part 3),
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1.4 × 10+
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1₂(aq) + I-¯(aq) 13¯(aq)
Keq = 750 (at 25 °C)
34. 1.0 × 104 mol I₂ and 4.0 × 10-³ mol KI are dissolved in
water at 25 °C to give 100.0 mL of solution. What is the
equilibrium concentration of I₂ in this solution?
(A) 1.3 x 10-6 M
(C) 5.0 x 10-4 M
(B) 3.4 x 10-5 M
(D) 5.3 x 10-3 M
35. Which changes will result in an increase in the number of
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(B) II only
(D) Neither I nor II
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tile. Do not combine terms.
Ka
=
= 1.8 × 10-5
[500.0]
[0.200]
RESET
[5.00]
[1.0 × 10-9]
[1.0 × 10-9]
[1.8 × 10-5]
[x + 5.00]
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[0]
[x-5.00]
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1
2
3
Based on your ICE table (Part 1) and the equilibrium expression, Ka (Part 2), determine
the original mass of solid CH3COONa added to create this buffer solution.
MNACH3COO
g
0
0.360
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21
43
11
15
36 x 10'
59 x 105
43 x 105
RESET
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in order to determine the unknown. Each reaction participant must be represented by
one tile. Do not combine terms.
Ка
=
RESET
[0]
[0.95]
[0.68]
[8.68]
[x]
[2x]
[2x]²
[0.95+x]
[0.95 - x]
[0.95 + 2x]
[0.95 -2x]
[0.68+x]
[0.68 - x]
[0.68 + 2x]
[0.68 - 2x]
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0.939
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2.09 × 10-º
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1
2
3
Based on your ICE table (Part 1) and the equilibrium expression for Ka (Part 2),
determine the pH of the buffer solution.
pH
RESET
0
19.65
5.46
0.95
0.022
8.53
3.4 × 10-€
2.9 × 10-9
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Indicate how each of the following will affect the equilibrium concentration of H20 in
the reaction: increase, decrease, or no change
2HF(g) + O,(g) + 76 kcal
S H,O (g) + OF2(g)
a.
Adding more OF2 (g)
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CO2 (aq) +
2 NH3 (aq)
CO(NH2)2 (aq)
H20 (1)
Ko = 3.54 x 10-8
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#
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E
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Energy diagrams for two reactions are shown.
Macmillan Learning
Energy (kJ/mol)
e
150
100
50-
What is the heat of reaction for Reaction A?
AHrxnA =
4
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What is the activation energy for Reaction A?
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Energy (kJ/mol)
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What is the heat of reaction for Reaction B?
AHxnB =
What is the activation energy for Reaction B?
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Time (min)
0.5
1
15
2
2.5
3
4.7
[Z] (mg/mL)
1
0.66
0.5
0.4
A. 5.1
B. 7.5
C. 9.5
D. 19.5
E. 14.8
0.334
0.286
0.192
From time zero, how long (in min) will it take for the drug's concentration to drop down to 0.05 mg/ml?
(Hint: While you can, you do not have to calculate Co to answer this question)
Rationale (YRI Chemical Kinetics and Drug Stability: Calculations: Please refer to calculations of the variou
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26. Which of the following statements is true about the I.C.E. table below for the reaction: 3H2(g) + N2(g)
at a given temperature.
3H2(g)
N2(g)
2 2NH3(g)
0.24 M
0.52 M
C
E 0.84 M
S
a) y = + 0.60 M
b) z = + 0.80 M
c) t = + 0.12 M
d) s = + 0.80 M
e) none of the above
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ACTIVITY TASK
Activity 6
State the type of Chemical Reaction
1. BaCl, + H,SO →
2. CH12 + O2→
3. Zn + CuSO,→
4. Cs + Br, >
5. FeCO, →
1SPU SELE-PACED LEARNING MOnuLE: PHYSICAL SCIENCE
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60
50
40
kcal/mol 30
20
10
course of rx
The reaction requires a constant input of energy to proceed
A. True
B. False
Reset Selection
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a)
HJinitinl
Rate in M-s
2.5 x 10
Experiment
initial
1
0.0020 M
0.0050 M
2
0.0020 M
0.0025 M
1.3 x 10
0.0015 M
0.0025 M
1.3 x 10
4.
0.0050 M
0.0010 M
0.5 x 103
According to the experimental data and by considering the reaction given below,
find and demonstrate the way to calculate the rate law. Explain each step.
Initial rate data: 2H,(g) + Cl{g) –→ 2HCI(g)
b)
Consider this reaction.
4NH,(g) + 30,(g) 2N{g) + 6H,O(!)
If the rate of formation of N, is 0.10 M-s, what is the corresponding rate of disappearance of O,?
Explain step by step how to calculate the target value.
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Part 1: Making Sandwiches:
O Cheese
4 slices
1) The
is a simulation of a two-reactant synthesis reaction.
2) Take some time and familiarize yourself with the simulation.
6 slices
8 slices
3) Set the reaction to a simple mole ratio of 2:1:1
4) Complete the table below while making tasty cheese sandwiches:
Bread Used
Cheese Used
2 slices
3 slices
28 02
5
AD
Reactants
PRE
5
2
3
Sandwiches
Made
Products
5 sandwiches
4 sandwiches
Leftovers
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e HW 11/10
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BIUA
Normal text
Helvetica...
11
2
3
Which letter correctly labels the reactants in the chemical reaction?
4AI +
302 2 Al203
C
A. A
В. В
С. С
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The graphs below show the relative concentration of N₂O4(g) and NO2(g)
as various stresses are exerted on the equilibrium system
N₂O4(g) + heat 2 NO2(g).
(Note: The graphs are not drawn to scale.)
Graph M
Concentration (mol/L)
Concentration (mol/L)
Graph N
Graph M
Graph P
N₂O4(2)
Graph O
NO 20
Reaction coordinate
N₂OA
NO2(g)
Graph O
Reaction coordinate
1.
2.
3.
Concentration (mol/L)
Match each of the graphs with the appropriate stress.
4.
Concentration (mol/L)
N₂O)
NO ₂0
Reaction coordinate
N₂O)
NO 21
Graph N
Graph P
Reaction coordinate
removing NO2(g)
cooling system
adding heat
adding N₂O4(g)
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Direction: Complete the following table. Write your answer on a separate sheet
of paper.
Equilibrium
Reaction
Effect
Keq
expression
Stress
Equilibrium
shift (encircle
your answer)
Forward
applied
(encircle
your answer)
Ha + Cla =
| 2HCI
Decreasing
the pressure
(increase,
decrease, no
change) in
the number
(HCIJ
Keq -
Backward
No Shift
of moles of
HCl(g)
(increase,
decrease, no
change) in
the volume of
Increasing
Fe,O +4 Ha
+ heat 2
Forward
Keq =
the
Backward
3Fe + 4H,O
temperature
No Shift
water vapor
collected
of (increase,
decrease, no
change)
the number
of moles of
NO
2NO + Oz
2NO + heat
Forward
Backward
No Shift
Addition
(NO,P
|NO]F|0,]|
Keq =
helium
Forward
H,CO» =
CO2 + H,O
Removal
of (increase,
decrease, no
change) in
the amount
Keq -
(H,CO,
CO2
Backward
No Shift
of H,CO,
(increase,
decrease, no
change)
in
amount of o,
(increase,
the volume of decrease, no
change)
in the
Increasing
the
Forward
Backward
No Shift
Keq=
temperature
the
4 NH3%g + 502
2 4NO+ 6…
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O The reaction rate decreases.
What mass of NaCl in grams is needed to prepare 2,500 g of 1.5% (m/m) NaCI
solution? *
380 g NaCl
O 38 g NaCl
O 1.67 g NaCI
3.8 g NaCI
You add solute to a solution and notice that all the solute crystallizes. The origin
solution was
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For the reaction: 2 H2(g) + O2(g) = 2 H20(g) at a certain temperature the
Keg is 1.8x105
If the concentrations in a reaction vessel at a given time are [H2] = 3.0 mol/L,
[02] = 2.0 mol/L and [H,O] = 0.010 mol/L, which of the following statements
is true?
%3D
%3D
%3D
The system is not at equilibrium, the reaction will proceed to the left
O The system is at equilibrium since Q = K
O The E, for the forward reaction is very large
The system is not at equilibrium, the reaction will proceed to the right
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MISSED THIS? Watch KCV 13.4; Read Section 13.4. You can click on
the Review link to access the section in your e Text.
Review | Constants | Periodic lable
100
Part A
90
A KCl solution containing 44 g of KCl per 100.0 g of water is cooled from 70 °C to 0 °C. What happens during cooling?
80 -
NaNO
70
O At 70 °C the solution is unsaturated, but by 0 °C the solution is saturated; therefore a precipitate will form.
60 -
NaSO4
O At 70 °C the solution is supersaturated, but by 0 °C the solution is unsaturated; therefore no precipitate will form.
50 -
KCI
At 70 °C the solution is supersaturated; therefore a precipitate will form upon cooling.
40 -
O At 70 °C the solution is unsaturated, and at 0 °C the solution is also unsaturated; therefore no precipitate will form.
NaCl
30-
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Solubility (g solute in 100 g H¿O)
CaCl
Pb(NO,)2
KNO3
KCrzO,
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The radioisotope phosphorus-32 is used in tracers for measuring phosphorus uptake by plants. The half-life of phosphorus-32 is 14.3 days. If you begin with 40.4 mg of this isotope, what mass remains after 22.3 days have passed?_____mg
42.0 mL sample of a 0.476 M aqueous hydrofluoric acid solution is titrated with a 0.305 M aqueous barium hydroxide solution. What is the pH after 19.9 mL of base have been added? Ka for HF is 7.2 × 10^-4 pH =____
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Reaction 1:
X2Y
30
Reaction 2:
K undergoes the two competing reactions represented above. The following graph shows the changes in energy that occur as the two reactions take place.
Y
Reaction 1
Reaction 2
Reaction Coordinate
In an experiment done at a low temperature, one hour after the reaction started, Y was produced but almost no Z was produced. At a much higher temperature, one hour after the reaction started, both Y and
Z had been produced. Which of the following best explains why very little Z was produced at the lower temperature?
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Chem 11- Chemistry for Engineers
66
s Choose the correct reactants for the double displacement equation
below.
- K2SO4 + Fe(OH)3
a) FeSO4 + K2(OH)3
b) Fea(SO4)2 + KOH
c) Fez(SO2)a + KH
d) Fea(SO4)a + KOH
6. Balance the equation above with the correct reactants.
a) 1, 2, 1, 2
b) 1, 2, 3, 2
c) 1, 6, 3, 2
d) 1, 6, 1, 2
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- The reaction A(g) + 2B(g) C(g) was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate Kc for this reaction. Round off the answer to two significant digits. Group of answer choices 0.060 5.1 17 19 25arrow_forwardCHEMISTRY 1110L LAB REPORT: REACTIONS OF COPPER (Part B) 1. Reaction 4: a. Color of copper(II) sulfate b. Water solubility of copper(II) sulfate 2. Reaction 5: CuO + H₂SO4 → CuSO4 + Zn →>> - 5. Percent recovery (calculations) 3. Mass of copper metal recovered 4. Initial mass of copper (from Part A) CuSO4 + Cu + ZnSO4 + Zn + H₂SO4 a. Color of zinc metal (before reaction) b. Color/appearance of copper metal (after reaction) c. Color of solution before reaction d. Color of solution after reaction e. Color of hydrogen gas ZnSO4 H₂O blue Solid Water 6. Initials of instructor or teaching assistant (TA) own H₂ Name • Loona Alg busi Partner Desk # AR Solid metal-normal color 20arrow_forwardcem 5 5 Constants I P Part A The concentration of Br in a sample of seawater is 3.3 - 10 M. If a liter of seawater has a mass of 1.0 kg, the concentration of Br is ppm. O 3.3 O 0.33 O 0.0033 O 26 O 0.026 Submit Request Answerarrow_forward
- Based on your ICE table (Part 2) and the definition of Ka, set up the expression for Ka in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. Ка = = 3.2 × 10-9 RESET [0] [0.110] [0.220] [0.101] [0.229] [0.106] ☑ (x)] [2x] [0.110+x] [0.110-x] [0.220 + x] [0.220-x] [0.101 + x] [0.101 - x] [0.229 +x] [0.229-x] [0.106 + x] [0.106 - x] < PREV 2 3 Based on your ICE table (Part 2) and the equilibrium expression for Ka (Part 3), determine the pH of solution. pH = RESET 0 20.3 2.03 8.85 5.15 1.41 × 10-* 7.09 × 10-€ 0.110 0.958 1.96arrow_forwardAccording to the Arrhenius equation, what does the slope of the line on this graph represent? In(k) vs 1/T -5 -50200315 0.002 0.00325 0.0033 0.00335 0.0034 -5.4 + -5.6 y = -9253x + 24.504 25.8 -6 -6.2 -6.4 -6.6 -6.8 1/T a) 24.504 Ea b) -9253 = LnA c) -9253 -Ea d) -9253-Ea/R =arrow_forwardFor each of the following reactions, indicate if there is something wrong with the reaction. If something is wrong, say what it is.a) 2H2(g) + O2(g) 2H2O(l)b) C(s) + H2O(p) CO(g) + H2(g)c) N2(g) + H2(g) NH3(g)d) Cℓ2O7() + H2O(l) 2HBrO4(aq)arrow_forward
- Determine the pH of a solution of aspirin (acetylsalicylic acid, HC,H7O4) by constructing an ICE table, writing the equilibrium constant expression, and using this information to determine the pH. The Ka of aspirin is 3.3 × 104. Complete Parts 1-3 before submitting your answer. 1 2 3 NEXT 652 mg of aspirin (HC9H7O4) is dissolved in an aqueous solution of 237 mL aqueous solution. Fill in the ICE table with the appropriate value for each involved species to determine concentrations of all reactants and products. HC9H7O4(aq) + H₂O(1) Initial (M) Change (M) Equilibrium (M) ☐ 0 = H3O+(aq) + C9H7O4(aq) 2.75 x 10-3 3.62 × 10-3 1.53 x 10-5 15.3 0.0153 RESET +x -x 2.75 x 10-3 + x 2.75 x 10-3-X 3.62 x 10-3 + x 3.62 x 10-3-X 1.53 x 10-5 + X 1.53 x 10-5-x 15.3 + x 15.3 - x 0.0153 + x 0.0153 - xarrow_forwardBased on your ICE table (Part 2) and the definition of Ka, set up the expression for Ka in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. Ka = 2.9 × 10-8 RESET [0] (0.13] [0.37] (0.010] [0.040] [0.10] [0.40] [x] [2x] [0.13 + x) [0.13-x] [0.010+x] [0.010-x] [0.040 + x] [0.040 - x] [0.10+x] [0.10-x] [0.40+x] [0.40-x] PREV 2 Based on your ICE table (Part 2) and the equilibrium expression for Ka (Part 3), determine the pH of solution. pH = RESET 0 7.3 × 10* 5.86 18.74 1.4 × 10+ 0.13 8.14 0.89arrow_forwardProblems 34 and 35 are about the exothermic reaction of iodine with iodide ion shown below. 1₂(aq) + I-¯(aq) 13¯(aq) Keq = 750 (at 25 °C) 34. 1.0 × 104 mol I₂ and 4.0 × 10-³ mol KI are dissolved in water at 25 °C to give 100.0 mL of solution. What is the equilibrium concentration of I₂ in this solution? (A) 1.3 x 10-6 M (C) 5.0 x 10-4 M (B) 3.4 x 10-5 M (D) 5.3 x 10-3 M 35. Which changes will result in an increase in the number of moles of I₂(aq) present at equilibrium? I. Increasing the temperature II. Replacing the KI with an equal mass of Nal (A) I only (C) Both I and II (B) II only (D) Neither I nor IIarrow_forward
- Based on your ICE table (Part 1) and the definition of Ka, set up the expression for Ka in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. Ka = = 1.8 × 10-5 [500.0] [0.200] RESET [5.00] [1.0 × 10-9] [1.0 × 10-9] [1.8 × 10-5] [x + 5.00] [x + 1.0 × 10] [x-1.0 x 10 x + 1.0 × 10-] [x-1.0 × 10-] [x+1.8 × 10] [x-1.8 × 10%] [0] [x-5.00] < PREV 1 2 3 Based on your ICE table (Part 1) and the equilibrium expression, Ka (Part 2), determine the original mass of solid CH3COONa added to create this buffer solution. MNACH3COO g 0 0.360 30 21 43 11 15 36 x 10' 59 x 105 43 x 105 RESET 59 50arrow_forwardBased on your ICE table (Part 1) and the definition of Ka, set up the expression for Ka in order to determine the unknown. Each reaction participant must be represented by one tile. Do not combine terms. Ка = RESET [0] [0.95] [0.68] [8.68] [x] [2x] [2x]² [0.95+x] [0.95 - x] [0.95 + 2x] [0.95 -2x] [0.68+x] [0.68 - x] [0.68 + 2x] [0.68 - 2x] 8.68 0.939 4.79 × 10-* 2.09 × 10-º < PREV 1 2 3 Based on your ICE table (Part 1) and the equilibrium expression for Ka (Part 2), determine the pH of the buffer solution. pH RESET 0 19.65 5.46 0.95 0.022 8.53 3.4 × 10-€ 2.9 × 10-9arrow_forwardI need help with the expel nation for question 7 please!arrow_forward
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