Final Exam Study Questions CHEM 1311 Fall 2023_

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Dec 6, 2023

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Final Exam Study Questions Chemistry 1311 Fall 2023 --------------------------------------------------------------------------------------------------------------------- Of the following species, ________ will have bond angles of 120°. A) PH 3 B) ClF 3 C) NCl 3 D) BCl 3 E) All of these will have bond angles of 120°. An electron domain consists of _ A , B , & C _. A) a nonbonding pair of electrons B) a single bond C) a multiple bond The electron-domain geometry and the molecular geometry of a molecule of the general formula ABn will always be the same if ________. A) there are no lone pairs on the central atom B) there is more than one central atom C) n is greater than four D) n is less than four E) the octet rule is obeyed Consider the following species when answering the following questions:
(i) BCl 3 (ii) CCl 4 (iii) TeCl 4 (iv) XeF 4 (v) SF 6 For which of the molecules is the molecular geometry (shape) the same as the VSEPR electron domain arrangement (electron domain geometry)? A) (i) and (ii) B) (i) and (iii) C) (ii) and (v) D) (iv) and (v) E) (v) only The π bond in ethylene, H 2 C=CH 2 , results from the overlap of ________. A) sp3 hybrid orbitals B) s atomic orbitals C) sp hybrid orbitals D) sp2 hybrid orbitals E) p atomic orbitals What is the molecular shape of H 2 O? A) T-shaped B) tetrahedral C) linear D) trigonal pyramidal E) bent
At 1 atm, an unknown sample melt at 49.9 °C and boils at 209.5 °C. If the temperature is 0°C, what is the state of matter for the sample? A) solid and liquid in equilibrium B) liquid C) gas D) solid E) liquid and gas in equilibrium According to molecular orbital theory, the bond order of N-N in nitrogen gas is ________. A) 0 B) 1/2 C) 1 D) 2 E) 3 The more effectively two atomic orbitals overlap, ________. A) the more bonding MOs will be produced by the combination. B) the higher will be the energy of the resulting bonding MO and the lower will be the energy of the resulting antibonding MO. C) the higher will be the energies of both bonding and antibonding MOs that result. D) the fewer antibonding MOs will be produced by the combination. E) the lower will be the energy of the resulting bonding MO and the higher will be the energy of the resulting antibonding MO. The molecular geometry of the SiH 2 Cl 2 molecule is ________.
A) trigonal planar B) tetrahedral C) trigonal pyramidal D) octahedral E) T-shaped One significant difference between gases and liquids is that ________. A) a gas is made up of molecules B) a gas expands to fill its container C) a gas may consist of both elements and compounds D) gases are always mixtures E) All of the above answers are correct. Sodium bicarbonate is reacted with concentrated hydrochloric acid at 37.0 °C and 1.00 atm. The reaction of 6.00 kg of bicarbonate with excess hydrochloric acid under these conditions will produce ________ L of CO 2 . A) 1.09 × 10 2 B) 2.85 × 10 4 C) 1.82 × 10 4 D) 8.70 × 10 2 E) 1.82 × 10 3 A sample of an unknown volatile liquid was injected into a Dumas flask and heated until no visible traces of the liquid could be found. The flask and its contents were then rapidly cooled and reweighed. The atmospheric pressure and temperature during the experiment were 0.976 atm and 18.0 °C, respectively. The unknown volatile liquid was ________.
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