CHM 113 Practice Exam 4 Fall 2023
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Arizona State University, Tempe *
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Course
113
Subject
Chemistry
Date
Dec 6, 2023
Type
Pages
9
Uploaded by hermit_crabs
CHM 113—Prof. Darcy Kimball
Practice Exam 4
1
Circle your Recitation Section below:
R1
R2
R3
R4
R5
R6
R7
R8
R9
R10
R11
R12
R13
R14
Circle your Recitation Table Number below:
1
2
3
4
5
6
7
8
9
10
11
12
13
Unit 4 Practice Exam
CHM 113
Your Name
1.
You are responsible for the information on this page. Please read it carefully.
2.
Three pieces of information must be
printed
and
coded
on the scantron sheet:
Print and code
your
name
.
Print and code
your
10-digit affiliate ID
. The affiliate ID is the second sequence of numbers on your
University ID card (100-------- or 120 ------ ).
Be sure to BUBBLE IN
your
Exam Version
.
3.
Use only a #2 pencil.
You CANNOT use pen (the scantron machine cannot read it)!
4.
Do all calculations on the exam pages. Do not make any unnecessary marks on the answer sheet and
make sure any erasing is thorough.
5.
The exam consists of 25 questions worth 4 points each.
Make sure you have all pages.
6.
Choose the
one best
answer to each of the questions and mark your selection on the Scantron sheet.
Read all responses before making a selection.
Do not mark more than one selection.
7.
When you are finished, bring your ASU Student ID and turn in both your Scantron and exam booklet
to a proctor.
**IMPORTANT**
•
IF YOU ARE SITTING WHERE YOU WILL BE TEMPTED TO LOOK AT SOMEONE ELSE’S WORK (OR VICE VERSA)
PLEASE MOVE NOW.
•
KEEP YOUR TEST BOOKLET AND SCANTRON FORM COVERED DURING THE EXAM SO THAT NONE OF YOUR
NEIGHBORS CAN SEE THEM.
•
BE SURE TO SHOW ALL YOUR WORK IN YOUR EXAM BOOKLET. ONLY THE SCANTRON IS GRADED. BUT IF
ACADEMIC DISHONESTY BY YOU OR ONE OF YOUR NEIGHBORS IS SUSPECTED, WHAT YOU WRITE IN YOUR
TEST BOOKLET IS YOUR BEST PROOF THAT THE WORK IS YOUR OWN.
THE MINIMUM SANCTION FOR CHEATING ON AN EXAM IS A ZERO ON THAT EXAM. THE MAXIMUM PENALTY IS
EXPULSION FROM THE COURSE AND UNIVERSITY. PLEASE DO NOT MAKE ME EXERCISE THIS RULE AS I HAVE
DONE SO IN THE PAST.
•
You will be keeping your exam booklet for Exam 4, only turning in your scantron.
CHM 113—Prof. Darcy Kimball
Practice Exam 4
2
1.
Nonpolar, molecular compounds of low molecular weight tend to be gases at room temperature.
(Ch. 10) Which of the following is
least likely to be a gas
at room temperature?
A.
HCl
B.
LiCl
C.
H
2
D.
CH
4
2.
(Ch. 10) Which of the following would
decrease the pressure
of a sample of N
2
gas?
A.
Adding more N
2
B.
Increasing the temperature
C.
Decreasing the kinetic energy
D.
Decreasing the volume
E.
Adding neon gas
3.
A small bubble with a volume of 3.20 mL bubble rises from the bottom of a lake, where the
pressure is 5.41 atm and the temperature is 12.4°C, to the surface where the pressure is 743 torr
and the temperature is 28.5°C.
(Ch. 10) What is the final
volume of the bubble (in mL)
?
A.
24.6
B.
18.7
C.
17.2
D.
41.8
4.
(Ch. 10) How many
moles of gas
are present in a 50.0 L container at 22.0°C and 825 torr?
A.
0.603
B.
2.23
C.
1.70 x 10
3
D.
2.29 x 10
4
CHM 113—Prof. Darcy Kimball
Practice Exam 4
3
5.
Ammonium nitrite undergoes thermal decomposition to produce only gases according to the
reaction below.
𝑵𝑵𝑵𝑵
𝟒𝟒
𝑵𝑵𝑵𝑵
𝟐𝟐
(
𝒔𝒔
)
→
𝑵𝑵
𝟐𝟐
(
𝒈𝒈
) +
𝟐𝟐
𝑵𝑵
𝟐𝟐
𝑵𝑵
(
𝒈𝒈
)
(Ch. 10) What
volume (in L) of gas
is produced by the decomposition of 35.0 g of ammonium nitrite
at 525°C and 1.5 atm?
A.
16
B.
24
C.
72
D.
131
6.
The density of air at STP is 1.285 g/L.
(Ch. 10) Which of the following gases will
fill a balloon that
does NOT float
in air at STP?
A.
NO (
g
)
B.
CH
4
(
g
)
C.
NH
3
(
g
)
D.
Ne (
g
)
7.
A pressure vessel contains a mixture of carbon dioxide, CO
2
(P
CO2
= 3.78 atm) and oxygen,
O
2
(P
O2
= 6.00 atm) gases.
(Ch. 10) The
mole fraction
of
CO
2
is
, making the
mole-fraction
of
O
2
.
A.
0.39; 0.61
B.
0.61; 0.39
C.
0.63; 1.59
D.
1.59; 2.59
8.
Carbon dioxide (CO
2
) and an unknown gas start to effuse from a container and the CO
2
takes 4.69
times as long to escape as the unknown gas.
(Ch. 10)
True or False.
A likely identity for the unknown gas is
NO
2
(g)
.
A.
True
B.
False
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CHM 113—Prof. Darcy Kimball
Practice Exam 4
4
9.
(Ch. 10) Which noble gas is expected to show the
largest deviation
from the ideal gas behavior?
A.
helium
B.
neon
C.
argon
D.
krypton
E.
xenon
10.
(Ch. 11) In liquids, the
attractive intermolecular forces
are
.
A.
very weak compared with kinetic energies of the molecules.
B.
strong enough to keep the molecules confined to vibrating about their fixed lattice points.
C.
weaker than the repulsion forces.
D.
strong enough to hold molecules relatively close together but not strong enough to keep
molecules from moving past each other.
11.
Elemental iodine (I
2
) is a solid at room temperature.
(Ch. 11) What is the
dominant intermolecular force
that exists among different I
2
molecules in the
solid?
A.
dispersion forces
B.
dipole-dipole forces
C.
hydrogen bonds
D.
ion-dipole forces
12.
When NaCl dissolves in water, aqueous Na
+
and Cl
─
ions result.
(Ch. 11/13) The
dominant force of attraction
that exists between Na
+
and H
2
O is called a(n)
.
A.
dispersion force.
B.
dipole-dipole interaction.
C.
hydrogen bond.
D.
ion-dipole interaction.
CHM 113—Prof. Darcy Kimball
Practice Exam 4
5
13.
Propane (CH
3
CH
2
CH
3
) and acetaldehyde (CH
3
CHO) both have the same molar mass (44 g/mol) but
have different dipole moments (0.1 D for propane and 2.7 D for acetaldehyde).
(Ch. 11)
Compare
these two molecules in the table below for each property listed.
Property
Propane or Acetaldehyde?
highest boiling point
lowest surface tension
highest vapor pressure
highest critical temperature
14.
(Ch. 11) Which statements about
viscosity
are
true
?
(i)
Viscosity increases as temperature decreases.
(ii)
Viscosity increases as molecular weight increases.
(iii)
Viscosity increases as intermolecular forces increase.
A.
(i) only
B.
(ii) and (iii)
C.
(i) and (iii)
D.
(i) and (ii)
E.
(i), (ii) and (iii)
CHM 113—Prof. Darcy Kimball
Practice Exam 4
6
15.
Consider the phase diagram below for an unknown substance.
(Ch. 11) What is the
normal boiling point (in °C)
for this substance?
A.
20°C
B.
40°C
C.
60°C
D.
100°C
16.
Consider the phase diagram below for an unknown substance.
(Ch. 11) Which of the following pressure/temperature combinations is
incorrectly matched
with the
phase of the unknown substance?
A.
─10°C
and 1.0 atm (substance is in the solid phase)
B.
20°C and 0.75 atm (substance is in the liquid phase)
C.
30°C and 0.5 atm (substance is in the gas phase)
D.
60°C and 1.6 atm (substance is in the gas phase)
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CHM 113—Prof. Darcy Kimball
Practice Exam 4
7
17.
(Ch. 11/13)
What type(s) of intermolecular force(s)
exist between ammonia (NH
3
) and water (H
2
O)?
A.
dispersion forces only
B.
dispersion forces, dipole-dipole interactions
C.
dispersion forces, dipole-dipole interactions, hydrogen bonds
D.
hydrogen bonds only
18.
(Ch. 13) When
argon (in left bulb)
is allowed to mix with
neon (in right bulb)
after the stopcock is
opened, the argon
spontaneously disperses
throughout the neon because
.
A.
of the large attractive forces between argon and neon atoms.
B.
heat is released during mixing.
C.
mixing results in an increase in the overall energy of the system.
D.
the dispersion of argon atoms produces an increase in disorder.
19.
(Ch. 13) Which one of the following substances is
most likely to dissolve
in
benzene
(C
6
H
6
)?
A.
CH
3
CH
2
OH
B.
CF
4
C.
HBr
D.
NaCl
CHM 113—Prof. Darcy Kimball
Practice Exam 4
8
20.
A 30.0 g sample of potassium nitrate is dissolved in 100 g of water at 60°C. The solution is cooled
to 20.0°C and no precipitate is observed.
(Ch. 13)
True or False.
This solution is
supersaturated
.
Hint: Use the solubility curve of KNO
3
provided above to answer this question.
A.
True
B.
False
21.
(Ch. 13) Pressure has an
appreciable
effect on the
solubility of
in liquids.
A.
gases
B.
liquids
C.
solids
D.
solids and liquids
22.
(Ch. 13)
Colligative properties
of solutions include all of the following except the
upon
the addition of a solute to the solvent.
A.
depression of vapor pressure
B.
elevation of the boiling point
C.
elevation of the freezing point
D.
increase in the osmotic pressure
CHM 113—Prof. Darcy Kimball
Practice Exam 4
9
To receive completion credit for the Unit 4 Practice Exam, you must complete Practice Exam 4 in
Canvas. This document is a hard-copy of that practice exam. I will go over all of the answers for this
practice exam in my Exam 4 Review Session (will be conducted in Zoom and will be recorded).
23.
(Ch. 13) Which aqueous solution should have the
highest boiling point
?
A.
0.1
m
NaCl
B.
1
m
KCl
C.
0.01
m
CaCl
2
D.
10
m
CCl
4
24.
(Ch. 13) What is the
vapor pressure (in mmHg) of water
at 25°C above a solution prepared by
dissolving 25 g of urea (CO(NH
2
)
2
) in 75 g of water?
Hint: The vapor pressure of pure water at 25°C is 23.8 mmHg.
A.
2.2
B.
6.0
C.
18
D.
22
25.
(Ch. 13) What is the
new boiling point (°C)
of an aqueous solution that is 27.1% sodium nitrate by
mass?
Hint: The molal boiling point elevation constant for water is 0.52°C/
m.
A.
128.28
B.
104.54
C.
100.28
D.
2.27
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