Practice Exam 4_ Fall 2023

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Chemistry

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Dec 6, 2023

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NAME CHE 2603 PRACTICE EXAM 4 FALL 2023
NOMENCLATURE: Choose the correct IUPAC name for each of the structures below. If the correct name doesn’t appear, choose “none of the above.” (3 pts each) 1. a. (2R,3R)-2,3-butanediol b. (2R,3R)-butane-2,3-diol c. (2S,3R)-butane-2,3-diol d. (2S,3R)-2,3-butanediol e. none of the above 2. a. 1-ethoxy-3-ethylheptane b. 7-ethoxy-5-ethylheptane c. 5-ethyl-5-propoxyheptane d. 3-ethyl-1-ethoxyheptane e. none of the above 3. a. (2E)-2-methyl-6-isopropyl-heptene b. (2E)-3-isopropyl-2-heptene c. (2Z)-5-isopropyl-6-heptene d. (2Z)-3-isopropyl-2-heptene e. none of the above 4. a. 1,2-epoxy-1,1,3-trimethylcyclohexane b. 1,2-epoxy-1,3,3-trimethylcyclohexane c. 1-epoxide-1,3,3-trimethylcyclohexane d. 1-epoxy-1,1,3-trimethylcyclohexane e. none of the above
SHORT ANSWER AND DISCUSSION. 5 . Calculate the degrees of unsaturation for each of the following molecular formulas and draw a structure that is consistent. Show your work! [8 points] 6. In class, we discussed the following reactions and how they differ in their regioselectivity. Provide the product for each reaction and discuss why the regioselectivity is observed in each case. Draw diagrams to explain your answer.[10 points].
7. The following reaction yields multiple products (16 points). Use curved arrows to show the mechanism for the formation A. Use curved arrows to show the mechanism for the formation B. Use curved arrows to show the mechanism for the formation of C.
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