Study Guide for Chapters 4-6

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Apr 3, 2024

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Study Guide for Chapters 4 -6 Chapter 4: Chemical Reactions and Chemical Quantities State the meaning of each part of a chemical equation o What do the coefficients in a chemical equation stand for Translate word problems into chemical equations o memorize the 7 diatomic elements: Br 2 , I 2 , N 2 , Cl 2 , H 2 , O 2 , F 2 Balance chemical equations Calculate the amount of product obtained from a given amount of reactant o Convert grams of reactant to moles using molar mass o Convert moles of reactant to moles of product using mole ratios o Converts moles of product to grams using molar mass Identify the limiting reactant Solve problems involving a limiting reactant Calculate the theoretical yield in a reaction Calculate the percent yield of a reaction, given the actual yield Chapter 5: Introduction to Solutions and Aqueous Reactions Draw the structure of water, and label partial charges Describe: o electronegativity o polar o nonpolar o like dissolves like rule Define: o solute o solvent o aqueous solution o strong electrolyte (give examples) o weak electrolyte (give examples) o nonelectrolyte (give examples) o strong acids (give examples) o weak acids (give examples) o strong bases (give examples) o weak bases (give examples) o stock solution o standard solution Know the molarity equation o determine the molarity of a solution given the mass of solute and volume of solution o determine the molarity of each ion in a solution o determine the mass and/or volume of reagents necessary to prepare a solution of a given molarity o Describe the process of forming a standard aqueous solution: from a solid by dilution memorize the dilution equation: M 1 V 1 = M 2 V 2
Precipitation Reactions: Use solubility rules to predict determine which ionic compounds will be soluble in water o Write dissolution equations for ionic compounds, using the correct charge and number of each ion in solution o calculate the concentration of ions in solution Use solubility rules to predict the products of reactions in aqueous solution Write molecular, ionic, and net ionic equations to describe precipitation reactions in solution Solve problems involving precipitation reactions o use the molarity equation in stoichiometry problems Acid-Base Reactions: Define o Acid o Base o Analyte o Titrant o Endpoint o Equivalence point o monoprotic, diprotic, polyprotic Predict the products of acid-base reactions o Write molecular, ionic, and net ionic equations to describe acid-base reactions in water strong acid, strong base, weak acid, weak base Use the molarity equation to solve acid-base titration problems o Calculate the molarity and/or volume of the analyte o calculate the molar mass of the analyte Oxidation-Reduction Reactions: Define: o oxidation o reduction o oxidizing agent o reducing agent Assign oxidation states to atoms in a compound Identify which elements are oxidized and which are reduced in a reaction Identify which elements are acting as oxidizing agents and reducing agents in a reaction Chapter 6: Gases Use Kinetic Molecular Theory (KMT) to describe the behavior of gases on the molecular and macroscopic scale Know the Ideal Gas Law: PV = nRT o Solve problems using the ideal gas law o solve problems involving changing conditions by modifying the ideal gas law o Use the ideal gas law to solve for moles of a gas in a stoichiometry problem Know STP conditions: 1 atm pressure, 0 o C Use the relationship 1 mole of a gas = 22.4L at STP in stoichiometry calculations Calculate the density of a gas at STP
Calculate the density of a gas under non-STP conditions Know Dalton’s Law of Partial Pressures o Solve problems involving mixtures of gases o Solve problems involving collecting a gas over water Know the mole fraction equation o solve for the partial pressure of a gas within a mixture of gases Calculate o kinetic energy of a gas depending on its temperature o root mean square velocity of a gas depending on its temperature and molar mass Compare the rate of effusion of two gases o qualitatively o quantitatively Compare the distance of diffusion of two gases o qualitatively o quantitatively Real Gases o Describe why and how gases deviate from ideal behavior o under what conditions do you see the most deviation from ideal behavior? Chapter 4 Questions: 1. Balance the following chemical equations: a. ___AgI + ___Na 2 S ___Ag 2 S + ___NaI b. ___Mg(OH) 2 + ___HCl ___MgCl 2 + ___H 2 O c. ___TiCl 4 + ___H 2 O ___TiO 2 + ___HCl d. ___HNO 2 ___HNO 3 + ___NO + ___H 2 O 2. The following reaction is used to form lead(II) iodide crystals. What mass of lead(II) iodide could be formed from 250.0g of lead(II) acetate? Pb(C 2 H 3 O 2 ) 2 + 2KI PbI 2 + 2KC 2 H 3 O 2 3. A reaction combines 64.81g of silver nitrate with 92.67g of potassium bromide: AgNO 3 + KBr AgBr + KNO 3 a. Which reactant is limiting? Which is excess? b. What is the theoretical yield of silver bromide? c. If the actual yield of silver bromide is 14.77g, what was the percent yield? Chapter 5 Questions: 1. Write the dissociation equation for K 3 PO 4 in water. 2. Which of the following substances would be soluble in water? a. CH 3 CH 2 OH b. C 6 H 6 c. LiBr 3. Classify the following as strong, weak, or nonelectrolytes: a. CH 3 CH 2 OH b. HCl c. NH 3 4. What is the molarity of 49.74g of H 2 SO 4 dissolved in enough water to make 500.mL of solution? 5. Calculate the concentration of sodium ions in 0.25M Na 3 PO 4 6. Describe how you would prepare 250.mL of 1.0M Na 2 SO 4 7. Describe how you would prepare 500.mL of 1.0N H 2 SO 4 from 17.8M H 2 SO 4
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