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University of North Carolina, Chapel Hill *

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102L

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Chemistry

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Apr 3, 2024

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pdf

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CHEM 102L – Experiment 15.2 In-Lab Assignment Spring 2022 Name Minaal Khanna Lab Partner Gayatri Venkstesan Arushi Rathod UNC Onyen minaalk 10 Performance Points TA Use Only Experiment 15.2: In-Lab Assignment (40 Total Points) Instructions: The first part of this assignment should be completed with your lab partner. You are ALLOWED AND EXPECTED to work with your laboratory partner. However, experimental observations should be written in your own words. Your answers should not be word for word the same, if they are you will receive a zero for this assignment. Suggestions and Tips: Each table should have a title: a brief statement about the contents of the table. Always include units where necessary. Pay attention to significant figures when recording data. Do not resize any text boxes or tables. o Size: 11 pt font Always include units. Pay attention to significant figures. Standard deviations should be rounded to 1 sigfig; averages reported with S.D.’s should be rounded to the S.D.’s decimal level of precision. *Record the stock concentrations of HNO 3 and NaSCN to 3 significant figures. *Record mass to three decimal places and maximum absorption wavelength to one decimal place. PREPARATION OF AND MEASUREMENTS WITH THE EQUILIBRIUM SOLUTIONS Table 1 6 Points Table 1. Stock chemical data and iron thiocyanate abs. wavelength. Concentration of Stock HNO 3 Solution (M) 1.00 Mass of Fe(NO 3 ) 3 · 9H 2 O (g) 1.503 Concentration of Stock NaSCN Solution ( M ) 2.00*10 -3 λ max (nm) 452 Table 2 8 Points Table 2. Equilibrium iron thiocyanate absorbance readings with average and standard deviation reported. Absorbance Trial 1 Trial 2 Trial 3 Average ± Std. Dev. E1 .765 .761 .770 .765 +/- .005 E2 .614 .610 .622 .615+/- .006 E3 .654 .696 .707 .69+/- .03 E4 .857 .832 .858 .85 +/- .01 E5 .927 .958 .909 .93 +/- .02
CHEM 102L – Experiment 15.2 In-Lab Assignment Spring 2022 2 of 3 Figure 1 5 Points Figure 1. A picture of the 5 cuvette equilibrium sample solutions with the color of the samples visible in the picture. 1. 7 Total Points I.C.E. Tables : Using the data you collected for cuvette E3 and the molar absorptivity coefficient you determined last week, complete the I.C.E. table below. Be sure to use the correct number of significant figures. If you need a review, please see the appendix of the lab manual or your chemistry textbook. Step 1: 2 Point Write the complete balanced chemical equation with states for the reaction between Fe 3+ and SCN - to form [Fe(NCS)] 2+ . Note: How do you show that a reaction is in equilibrium? Fe 3+ +SCN - ßà Fe(SCN) 2+ Step 2: 1 Point Fill in the I.C.E. table below with the initial concentrations of each species in the cuvette E3. Step 3: 1 Point Determine the final concentration of the product. Place your answer into the I.C.E. table. Step 4: 1 Point B ased on your answer in step 3, what is the numerical change in concentration for all three species below? Include the appropriate signs for the loss of reactants or the formation of products. Place your answer in the I.C.E. table. Step 5: 2 Points What is the final concentration of Fe(NO 3 ) 3 •9H 2 O and NaSCN in the cuvette? Place your answer in the I.C.E. table below. Concentration of Fe(NO 3 ) 3 · 9H 2 O (M) Concentration of NaSCN (M) Concentration of [Fe(NCS)] 2+ (M) Initial 8.0*10 -3 1.4*10 -4 0 Change -1.2*10 -4 -1.2*10 -4 +1.2*10 -4 Final 7.9*10 -3 M 2.0*10 -5 M 1.2*10 -4 M
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