15.2 In lab
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CHEM 102L – Experiment 15.2 In-Lab Assignment Spring 2022
Name Minaal Khanna Lab Partner Gayatri Venkstesan Arushi Rathod
UNC Onyen minaalk 10 Performance Points TA Use Only Experiment 15.2: In-Lab Assignment (40 Total Points) Instructions: The first part of this assignment should be completed with your lab partner. You are ALLOWED AND EXPECTED to work with your laboratory partner. However, experimental observations should be written in your own words. Your answers should not be word for word the same, if they are you will receive a zero for this assignment.
Suggestions and Tips: •
Each table should have a title: a brief statement about the contents of the table. •
Always
include units where necessary. Pay attention
to significant figures when recording data. •
Do not resize any text boxes or tables.
o
Size: 11 pt font
•
Always
include units. Pay attention
to significant figures. Standard deviations should be rounded to 1 sigfig; averages reported with
S.D.’s should be rounded to the S.D.’s decimal level of precision. *Record the stock concentrations of HNO
3
and NaSCN to 3 significant figures.
*Record mass to three decimal places and maximum absorption wavelength to one decimal place.
PREPARATION OF AND MEASUREMENTS WITH THE EQUILIBRIUM SOLUTIONS Table 1 6 Points Table 1.
Stock chemical data and iron thiocyanate abs. wavelength. Concentration of Stock HNO
3
Solution (M)
1.00 Mass of Fe(NO
3
)
3 · 9H
2
O
(g)
1.503 Concentration of Stock NaSCN Solution
(
M
)
2.00*10
-3
λ
max
(nm)
452 Table 2 8 Points Table 2.
Equilibrium iron thiocyanate absorbance readings with average and standard deviation reported. Absorbance Trial 1 Trial 2 Trial 3 Average ± Std. Dev. E1 .765
.761
.770
.765 +/- .005
E2 .614
.610
.622
.615+/- .006
E3 .654
.696
.707
.69+/- .03
E4 .857
.832
.858
.85 +/- .01
E5 .927
.958
.909
.93 +/- .02
CHEM 102L – Experiment 15.2 In-Lab Assignment Spring 2022
2 of 3 Figure 1 5 Points Figure 1.
A picture of the 5 cuvette equilibrium sample solutions with the color of the samples visible in the picture. 1. 7 Total Points I.C.E. Tables
: Using the data you collected for cuvette E3 and the molar absorptivity coefficient you determined last week, complete the I.C.E. table below. Be sure to use the correct number of significant figures.
If you need a review, please see the appendix of the lab manual or your chemistry textbook. •
Step 1: 2 Point Write the complete balanced chemical equation with states for the reaction between Fe
3+
and SCN
-
to form [Fe(NCS)]
2+
. Note: How do you show that a reaction is in equilibrium? Fe
3+
+SCN
-
ßà
Fe(SCN)
2+
•
Step 2: 1 Point Fill in the I.C.E. table below with the initial concentrations of each species in the cuvette E3.
•
Step 3: 1 Point
Determine the final concentration of the product. Place your answer into the I.C.E. table.
•
Step 4: 1 Point B
ased on your answer in step 3, what is the numerical change in concentration for all three species below? Include the appropriate signs
for the loss of reactants or the formation of products. Place your answer in the I.C.E. table.
•
Step 5: 2 Points What is the final concentration of Fe(NO
3
)
3
•9H
2
O and NaSCN in the cuvette? Place your answer in the I.C.E. table below.
Concentration of Fe(NO
3
)
3
· 9H
2
O (M) Concentration of NaSCN (M) Concentration of [Fe(NCS)]
2+
(M) Initial 8.0*10
-3
1.4*10
-4
0 Change -1.2*10
-4
-1.2*10
-4
+1.2*10
-4
Final 7.9*10
-3
M 2.0*10
-5
M 1.2*10
-4
M
CHEM 102L – Experiment 15.2 In-Lab Assignment Spring 2022
3 of 3 2. 4 Points Using the equilibrium concentrations, what is the equilibrium equation for the system described above? What is the value of the equilibrium constant for cuvette E3? Show complete work with an equation builder and units (where applicable). Please report K
eq
without units. K
eq
=
["#(%&’)
!"
]
["#
#"
][%&’
$
]
= [*.,∗*./01]
[2.3∗*.^/56][,..∗*.
$%
]
= 7.6 ∗ 10^2
TA USE ONLY:
Please grade this/these question(s) once all other questions for all other sections have been graded. Submitted Late? Formatting Issues?
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solution.
☐ other: ☐
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O CHEM-3A-81091-2...
ead
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Part A
PCl5 (g) PC13 (1) + Cl2(g)
Use A for [PC15], B for [PC13], C for [Cl2].
ΜΕ ΑΣΦ
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2KNO3(s)
= 2KNO2 (s) + O2(g)
Use A for [KNO3], B for [KNO2], C for [02].
Keq =
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Fe(s) + 2HCI(aq)→→→FeCl₂(s) + H₂(g)
AH° = -7.4 kJ and AS° = 107.9 J/K
D2L
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The maximum amount of work that could be done when 2.08 moles of Fe(s) react at 286 K, 1 atm is
Assume that AH° and ASº are independent of temperature.
Retry Entire Group 4 more group attempts remaining
kj.
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23. Which of the following compounds contain a hemiacetal functional group?
OCH3
OH
но.
OCH3
A
OCH3
В
OCH3
C
a. A and B b. B and C
c. B only
d. C only
24. Which of the following compounds contains an acetal functional group?
OCH3
-OCH3
-OH
OCH3
A
B
a. A and B
c. B and C
b. A and C
d. C only
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- ethanol is commonly used as a fuel for cars and for heating homes.Based on your results,explain why ethanol makes a good fuelarrow_forwardCHEM 3428 Worksheet 3 Name TA/Section Score /27 All of this work will be incorporated into your lab report. Show all work, hand write legibly, and use complete sentences. Use correct units when applicable. Rubric Scoring For 3-point questions: 3 points - complete, correct without errors 2 points - on the right track, minimal omissions, or errors 1 point - attempt made, omissions and errors 0 points - no answer 1. (3 pts) Draw a scheme for the epoxidation with Oxone reaction. Include all reagents and reaction conditions. 2. (3 pts) What is the theoretical yield of this reaction as described in the procedure section of the module page in mmol and in g? Report the theoretical yield using proper format. Show all your calculations.arrow_forwardDocument1 - Word Search (Alt+Q) References Mailings Review View Help Write the corresponding letters to the following descriptions. Each proposal can be associated with 0 or 1 match and each letter is not necessarily associated with a proposal. a. [Ar] 4s? b. 1s 2s2p63s23p3 c. 1s2s2p2 d. [Ne] 3s23ps e. [Ar] 4s23d10 f. 1s22s! g. None of those answers 1. I am a halogen 2. I am a transition metal 3. I am alkaline 4. I have exactly 2 single electrons 5. I am the smallest of the atoms presented here 6. I have exactly 3 valence electrons 7.I am the most paramagnetic of the atoms presented here 8. I am the copper 9.I am isoelectronic with Ti2+ IF cessibility: Good to go IA 16 SISarrow_forward
- I need the answer for this question as Sage Math Code. It's a linear algebraarrow_forward24arrow_forward← 5 $24 CHEM 107-02 Exam 1: Ju x 5 ALEKS X A ALEKS - Julianna Graham - Lex + www-awu.aleks.com/alekscgi/x/Isl.exe/10_u-lgNslkr7j8P3JH-IQUHIQg6bJxmeSyVPHOEB1plef9xyC5Ca9Qld CzyNjpf1orelUZCXOUPfJMZe5q2zqwE61GUYcoDhTCI-Qs_... O Chemical Reactions Percent yield of chemical reactions 0/3 Julianna Gaseous ethane (CH3CH3) reacts with gaseous oxygen gas (02) to produce gaseous carbon dioxide (CO2) and gaseous water (H2O). If 1.97 g of carbon dioxide is produced from the reaction of 1.5 g of ethane and 3.1 g of oxygen gas, calculate the percent yield of carbon dioxide. Round your answer to 2 significant figures. 0 % Explanation Check X G MacBook Air ala 2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forward
- Home CHE101 02: Intro to Genera X b Answered: x CHE101_02: Int X (181) Primer Beso - You 101 Chem 101 х X app.101edu.co myClackamas Login CUnofficial Transcri... W Logon Oregon Scholarsh... Home FAFSA on... Welcome to the ... The National Soci... Apps Submit Question 8 of 8 How many grams of CO2 can be produced from the combustion of 8.84 moles of butane according to this equation: 2 CAH10(g)13 O2 (g) 8 CO2 (g) + 10 H2O (g) g 1 2 6 с 7 8 +/- 0 x 100 10:06 PM Type here to search ENG 11/13/2019 X + LOarrow_forwardلا © Macmillan Learning H H-C-OH H₂/Pt HO-C-H $ % do LO 5 H₂C-OH OCT 11 <6 Y MacBook Pro Resources Q2Q Erase Select Draw Templates More /// C 0 H G c 2Q & * ( 7 8 9 0 ) U 0 P SUDarrow_forwardChrome File Edit View History Bookmarks Profiles email draft - Google Docs sc ● Consider this reaction: 1 A ALEKS- Lara Althawadi - Lear X ☆ C www-awu.aleks.com/alekscgi/x/lsl.exe/1o_u-IgNsikr7j8P3jH-IvTqeviKFP6W0cqJcWJdIACROQwyw24GWHInUUz9jGCwQIcISUzhOQhHxz_5bM9yeRdQ... 17.4 Solubility and.... 5.3 Enthalpies of... 18.5 Gibbs Free E...Reading Schedule 19.6 Reduction Po... Y SOLUTION: The le... Math 115 W-S Fall... 2H, PO₂ (aq) → P₂O, (aq) + 3H₂O (aq) - At a certain temperature it obeys this rate law. -1 rate = (82. M¹-s¹) [H₂PO4] Q A 18.3 Gibbs Free E... O KINETICS AND EQUILIBRIUM Using first- and second-order integrated rate laws Os Explanation F N 18.210 @ x Nancy Foldi - Department of PX Suppose a vessel contains H₂PO4 at a concentration of 0.290M. Calculate how long it takes for the concentration of H₂PO4 to decrease by 92.%. You may assume no other reaction is important. Round your answer to 2 significant digits. 2 W Check S # X :m 3 26 9.f E Tab D 14 $ 4 Window Help C X R Ś F JO…arrow_forward
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