CHE-109-Fall-2019-Exam-3-W_Key

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University of Kentucky *

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Chemistry

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Jan 9, 2024

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CHE 109 Fall 2019 Exam 3 Your Name: Your ID: Question #: 1 For each substance, determine the oxidation number of the Cl. Report each answer as a whole number. Substance Oxidation Number on Cl Cl 2 1 NaClO 4 2 1. 2. ____________________________________________________________________________ Question #: 2 What is the oxidation number of Mn in MnO 4 ? A. +7 B. +6 C. +8 D. +4 ____________________________________________________________________________ Question #: 3 Which one is a redox reaction? A. CH 4 ( g ) + 2O 2 ( g ) CO 2 ( g ) + 2H 2 O( l ) B. Na 2 S( aq ) + Fe(NO 3 ) 2 ( aq ) FeS( s ) +2NaNO 3 ( aq ) C. NH 4 Cl( aq ) + KOH( aq ) H 2 O( l ) + KCl( aq ) + NH 3 ( g ) D. K 2 SO 4 ( aq ) + BaCl 2 ( aq ) BaSO 4 ( s ) + 2KCl( aq ) ____________________________________________________________________________
Question #: 4 For the reaction, Fe( s ) + Cu(NO 3 ) 2 ( aq ) Fe(NO 3 ) 2 ( aq ) + Cu( s ) . A. Cu loses electrons and is oxidized. B. Cu gains electrons and is oxidized. C. Cu loses electrons and is reduced. D. Cu gains electrons and is reduced. ____________________________________________________________________________ Question #: 5 Which element is oxidized in the reaction? Fe 2 O 3 + Al Al 2 O 3 + Fe . A. Fe B. O C. Al ____________________________________________________________________________ Question #: 6 In the reaction, 1 [Fe, C, O] is the oxidizing agent and 2 [Fe, C, O] is the reducing agent. 2Fe 2 O 3 ( s ) + 3C( s ) 4Fe( s ) + 3CO 2 ( g ) 1. 2. ____________________________________________________________________________
Question #: 7 For the redox reaction below: Determine the products, if any, that would be formed including any coefficients needed to balance the reaction. 2AgNO 3 ( aq ) + Cu( s ) . A. CuNO 3 (aq) + Ag(s) B. CuNO 3 (aq) + 2Ag(s) C. Cu(NO 3 ) 2 (aq) + Ag(s) D. Cu(NO 3 ) 2 (aq) + 2Ag(s) E. No reaction ____________________________________________________________________________ Question #: 8 When 0.350 moles of HCl react with excess aluminum, how many moles of hydrogen are produced according to the reaction? 2Al( s ) + 6HCl( aq ) 2AlCl 3 ( aq )+3H 2 ( g ) 1 mol H 2 Report your answer with three significant figures. Do NOT include units in your answer. 1. ____________________________________________________________________________ Question #: 9 How many grams of Li 3 N can be formed from 2.40 moles of Li react with an excess of N 2 ? molar mass of Li 3 N = 34.8 g/mol 6 Li( s ) + N 2 ( g ) 2 Li 3 N( s ) . A. 20.0 g Li3N B. 27.9 g Li3N C. 42.0.1 g Li3N D. 83.6 g Li3N ____________________________________________________________________________
Question #: 10 Methanol reacts with oxygen according to the reaction: 2CH 3 OH+ 3O 2 2CO 2 + 4H 2 O If 0.5 moles of CH 3 OH react with 0.8 moles of O 2 , what is the limiting reactant? 1 [methanol, oxygen] 1. ____________________________________________________________________________ Question #: 11 How many grams of oxygen (molar mass = 32.0 g/mol) can be obtained from the decomposition of 0.150 moles of potassium chlorate? 2 KClO 3 ( s ) 2 KCl( s ) + 3 O 2 ( g ) A. 7.20 g B. 2.40 g C. 3.40 g D. 14.4 g ____________________________________________________________________________ Question #: 12 For the reaction: NaCl( s ) + AgNO 3 ( aq ) AgCl( s ) + NaNO 3 ( aq ) 16 grams of NaCl is added to 100 mL of a 2.0 M AgNO 3 solution. The AgCl precipitate was collected, dried, and weighed, and found to have a mass of 23 g. Which measurement, if any, is the actual yield? A. 23 g AgCl B. 16 g NaCl C. 100 mL of 2.0 M AgNO 3 D. None of the above, the actual yield must be calculated from the values given. ____________________________________________________________________________
Question #: 13 How much excess reactant remains after 1.50 g of lithium (molar mass = 6.94 g/mol) and 1.50 g of nitrogen (28.0 g/mol) combine to form lithium nitride (molar mass - 34.8 g/mol) according to the following chemical equation? 6Li + N 2 2Li 3 N A. 0.25 g B. 0.50 g C. 0.75 g D. 1.0 g ____________________________________________________________________________ Question #: 14 Ethylene reacts with water according to the following reaction: C 2 H 4 ( g ) + H 2 O( l ) C 2 H 5 OH( l ) If the reaction has a theoretical yield of 57 grams of ethanol, but only 37 grams are produced, what is the percent yield of the reaction? 1 % Report your answer with two significant figures. Do NOT include units or the percent sign in your answer. 1. ____________________________________________________________________________ Question #: 15 For the reaction: BaCl 2 ( aq ) + K 2 SO 4 ( aq ) BaSO 4 ( s ) + 2KCl( aq ) 15 grams of BaCl 2 (208.2 g/mol) were added to 100 mL of a 2.0 M K 2 SO 4 solution. The amount of BaSO 4 (233.4 g/mol) precipitate obtained in this reaction was 12.9 g. If the percent yield is 75%, what is the theoretical yield of BaSO 4 ? A. 47.7 g BaSO 4 B. 17.2 g BaSO 4 C. 22.9 g BaSO 4 D. 2.20 g BaSO 4 ____________________________________________________________________________
Question #: 16 What volume of a 0.300 M KCl solution will completely react with 2.00 L of a 0.200 M Pb(NO 3 ) 2 solution? 2KCl (aq) + Pb(NO 3 ) 2 (aq) PbCl 2 (s) + 2KNO 3 (aq) . A. 2.67 L B. 3.92 L C. 4.51 L D. 5.33 L ____________________________________________________________________________ Question #: 17 What volume of 0.550 M phosphoric acid is needed to react completely with 15.00 mL of 0.217 M KOH? H 3 PO 4 ( aq ) + 3KOH( aq ) K 3 PO 4 ( aq ) + 3H 2 O( l ) . A. 11.7 mL B. 4.69 mL C. 1.97 mL D. 38.1 mL ____________________________________________________________________________ Question #: 18 What does "capacity to do work" refer to? A. Thermal equilibrium B. Energy C. First law of thermodynamics D. System ____________________________________________________________________________ Question #: 19
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