(1) A drug with a molecular mass of 292.16 was dissolved in a 5.00 mL volumetric flask. A 1.00 mL aliquot was withdrawn, placed in a 10.00 ml volumetric flask, and diluted to the mark. The absorbance at 340 nm was 0.427 in a 1.00 cm cuvette. The molar absorptivity for this compound at 340 nm is 6130 M1 cm1. Calculate the concentration of compound in the cuvette? What will be the absorbance if the path length was decreased to 0.50 cm?

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.26P
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Question 25
(1) A drug with a molecular mass of 292.16 was dissolved in a 5.00 mL volumetric flask. A 1.00 mL aliquot was withdrawn, placed in
a 10.00 ml volumetric flask, and diluted to the mark. The absorbance at 340 nm was 0.427 in a 1.00 cm cuvette. The molar
absorptivity for this compound at 340 nm is 6130 M-1 cm-1. Calculate the concentration of compound in the cuvette? What will
be the absorbance if the path length was decreased to 0.50 cm?
(2) The solubility product values Ksp for three silver halides are given blow:
AgBr =5.2 x 10-13 , AgCl = 1.8 x 10-10 , AglO3 =3.0 x 10 -8
In perception titration between these halide solutions and AgNO3 solution. Which halide give the sharpest end point? and Why?
Use the editor to format your answer
Transcribed Image Text:Question 25 (1) A drug with a molecular mass of 292.16 was dissolved in a 5.00 mL volumetric flask. A 1.00 mL aliquot was withdrawn, placed in a 10.00 ml volumetric flask, and diluted to the mark. The absorbance at 340 nm was 0.427 in a 1.00 cm cuvette. The molar absorptivity for this compound at 340 nm is 6130 M-1 cm-1. Calculate the concentration of compound in the cuvette? What will be the absorbance if the path length was decreased to 0.50 cm? (2) The solubility product values Ksp for three silver halides are given blow: AgBr =5.2 x 10-13 , AgCl = 1.8 x 10-10 , AglO3 =3.0 x 10 -8 In perception titration between these halide solutions and AgNO3 solution. Which halide give the sharpest end point? and Why? Use the editor to format your answer
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