1. Determine the Reaction Order for HCl using calculations described in the background section. Show your work. Note that your answer will probably not be a whole number as it is in the examples, so round to the nearest whole number. 2. Determine the Reaction Order for Na2S2O3 using calculations described in the Background section. Show your work. Note that your answer will probably not be a whole number as it is in the examples. 3. Write the rate law for the reaction between HCl and Na2S2O3.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter7: Statistical Data Treatment And Evaluation
Section: Chapter Questions
Problem 7.26QAP
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1. Determine the Reaction Order for HCl using calculations described in the background section. Show your work. Note that your answer will probably not be a whole number as it is in the examples, so round to the nearest whole number.

2. Determine the Reaction Order for Na2S2O3 using calculations described in the Background section. Show your work. Note that your answer will probably not be a whole number as it is in the examples.

3. Write the rate law for the reaction between HCl and Na2S2O3.

4. Describe sources of error in this experiment?

Data Table 1: Varying Concentrations of HCI
Well #C1, D1
12
of Drops of
HCI
of Drops of 0
H₂O
# of Drops of 8
Na₂S₂O₂
Concentration 1.0
(M) of
HCI Stock
Solution
Concentration 0.30
(M) of
Na₂S₂O3
Stock
Solution
Reaction
Concentration
(M) of HCI
after Mixing in
Well
Reaction
Concentration
(M) of
Na₂S₂O3 after
Mixing in Well
Trial 1
Reaction
Time (sec)
Trial 2
Reaction
Time (sec)
Average
Reaction
Time (sec)
Reaction
"Rate" (sec¹)
0.60
0.12
23.46
30.03
26.7
0.0375
Well #C2, D2
6
6
8
1.0
0.30
0.15
0.12
41.15
31.22
36.2
0.0276
Well #C3, D3
4
8
8
1.0
0.30
0.06
0.12
46.12
37.12
41.6
0.0240
Transcribed Image Text:Data Table 1: Varying Concentrations of HCI Well #C1, D1 12 of Drops of HCI of Drops of 0 H₂O # of Drops of 8 Na₂S₂O₂ Concentration 1.0 (M) of HCI Stock Solution Concentration 0.30 (M) of Na₂S₂O3 Stock Solution Reaction Concentration (M) of HCI after Mixing in Well Reaction Concentration (M) of Na₂S₂O3 after Mixing in Well Trial 1 Reaction Time (sec) Trial 2 Reaction Time (sec) Average Reaction Time (sec) Reaction "Rate" (sec¹) 0.60 0.12 23.46 30.03 26.7 0.0375 Well #C2, D2 6 6 8 1.0 0.30 0.15 0.12 41.15 31.22 36.2 0.0276 Well #C3, D3 4 8 8 1.0 0.30 0.06 0.12 46.12 37.12 41.6 0.0240
Data Table 2: Varying Concentrations of Na₂S₂O3
Well #C4, D4
#of Drops of 8
HCI
#of Drops of 0
H₂O
# of Drops of 12
Na₂S₂O3
Concentration 1.0
(M) of
HCI Stock
Solution
Concentration 0.30
(M) of
Na S₂0₂
Stock
Solution
Reaction
Concentration
(M) of HCI
after Mixing in
Well
Reaction
Concentration
(M) of
Na₂S₂O, after
Mixing in Well
Trial 1
Reaction
Time (sec)
Trial 2
Reaction
Time (sec)
Average
Reaction
Time (sec)
Reaction
"Rate" (sec¹)
0.4
0.28
31.12
25.29
43.8
0.0228
Well #C5,D5
8
6
1.0
0.30
0.4
0.045
53.24
57.47
82
0.0122
Well #C6, D6
8
8
4
1.0
0.30
0.4
0.02
89.86
84.93
129.9
0.0077
Transcribed Image Text:Data Table 2: Varying Concentrations of Na₂S₂O3 Well #C4, D4 #of Drops of 8 HCI #of Drops of 0 H₂O # of Drops of 12 Na₂S₂O3 Concentration 1.0 (M) of HCI Stock Solution Concentration 0.30 (M) of Na S₂0₂ Stock Solution Reaction Concentration (M) of HCI after Mixing in Well Reaction Concentration (M) of Na₂S₂O, after Mixing in Well Trial 1 Reaction Time (sec) Trial 2 Reaction Time (sec) Average Reaction Time (sec) Reaction "Rate" (sec¹) 0.4 0.28 31.12 25.29 43.8 0.0228 Well #C5,D5 8 6 1.0 0.30 0.4 0.045 53.24 57.47 82 0.0122 Well #C6, D6 8 8 4 1.0 0.30 0.4 0.02 89.86 84.93 129.9 0.0077
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