1. Occasionally, a crossed Cannizzaro reaction is carried out to reduce benzaldehyde derivatives to the corresponding benzyl alcohol, utilizing formaldehyde as the reducing agent. i) Please show the mechanism by which this occurs. ii) Why is this method'effecti ve? That is, why are the principal products benzyl alcohol and formic acid and not benzoic acid and methanol?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 42CTQ
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please solve second question

1. Occasionally, a crossed Cannizzaro reaction is carried out to reduce benzaldehyde
derivatives to the corresponding benzyl alcohol, utilizing formaldehyde as the
reducing agent.
i) Please show the mechanism by which this occurs.
ii) Why is this method'effective? That is, why are the principal products benzyl alcohol
acid and not benzoic acid and methanol?
Transcribed Image Text:1. Occasionally, a crossed Cannizzaro reaction is carried out to reduce benzaldehyde derivatives to the corresponding benzyl alcohol, utilizing formaldehyde as the reducing agent. i) Please show the mechanism by which this occurs. ii) Why is this method'effective? That is, why are the principal products benzyl alcohol acid and not benzoic acid and methanol?
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