Question
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Can you help me please solve all parts of question 1? (1 a, b, c, d, and e)

1.
Sketch the MO diagram for HCO3-
a.
Draw the Lewis structure and count the number of valence electrons
b.
Assign hybridization of all the atoms
i.
Determine hybridization of the center atom(s)
c. Identify and sketch o-framework
i. Identify number ofo bonds in the molecule and the number of e-involved
ii. Identify number of lone pairs and the number of e involved
d.
Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can
participate in r bonds.
i. Determine the number of electrons involved in the π bonds
ii. Count the p AOs not involved in hybridization
e.
Sketch the corresponding π MO and corresponding energy diagram for just T-framework.
i. Rank them in terms of increasing energy (depending on number ofloops)
ii. Fill the t MO's with the electrons involving in t bonds
ii. Label the t MO's as bonding, antibonding and/or nonbonding
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Transcribed Image Text:1. Sketch the MO diagram for HCO3- a. Draw the Lewis structure and count the number of valence electrons b. Assign hybridization of all the atoms i. Determine hybridization of the center atom(s) c. Identify and sketch o-framework i. Identify number ofo bonds in the molecule and the number of e-involved ii. Identify number of lone pairs and the number of e involved d. Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can participate in r bonds. i. Determine the number of electrons involved in the π bonds ii. Count the p AOs not involved in hybridization e. Sketch the corresponding π MO and corresponding energy diagram for just T-framework. i. Rank them in terms of increasing energy (depending on number ofloops) ii. Fill the t MO's with the electrons involving in t bonds ii. Label the t MO's as bonding, antibonding and/or nonbonding
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