1. Sketch the MO diagram for HCO3- a. Draw the Lewis structure and count the number of valence electrons b. Assign hybridization of all the atoms i. Determine hybridization of the center atom(s) c. Identify and sketch o-framework i. Identify number ofo bonds in the molecule and the number of e-involved ii. Identify number of lone pairs and the number of e involved d. Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can participate in r bonds. i. Determine the number of electrons involved in the π bonds ii. Count the p AOs not involved in hybridization e. Sketch the corresponding π MO and corresponding energy diagram for just T-framework. i. Rank them in terms of increasing energy (depending on number ofloops) ii. Fill the t MO's with the electrons involving in t bonds ii. Label the t MO's as bonding, antibonding and/or nonbonding
1. Sketch the MO diagram for HCO3- a. Draw the Lewis structure and count the number of valence electrons b. Assign hybridization of all the atoms i. Determine hybridization of the center atom(s) c. Identify and sketch o-framework i. Identify number ofo bonds in the molecule and the number of e-involved ii. Identify number of lone pairs and the number of e involved d. Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can participate in r bonds. i. Determine the number of electrons involved in the π bonds ii. Count the p AOs not involved in hybridization e. Sketch the corresponding π MO and corresponding energy diagram for just T-framework. i. Rank them in terms of increasing energy (depending on number ofloops) ii. Fill the t MO's with the electrons involving in t bonds ii. Label the t MO's as bonding, antibonding and/or nonbonding
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter10: Molecular Structure And Bonding Theories
Section: Chapter Questions
Problem 10.99QE: The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species....
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