1.0 g of a solid sample known to contain a mixture of NaOH and Na2CO3 is dissolved with distilled water and completed to 25 mL. By adding 2 drops of phenolphthalein (pT = 9.0) to the solution obtained, it was titrated with 0.107 M calibrated HCl solution, and the consumption was determined as 10.6 mL. Subsequently, 2 drops of methyl red (pT = 4.4) were added onto the same solution and titrated, the consumption was determined as 6.1 mL. Accordingly, calculate the amount of NaOH and Na2CO3 in the sample solution as% (a/a) by writing the related reactions. (Na: 23, C: 12, O: 16, H: 1 g / mol)

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter4: Stoichiometry: Quantitative Information About Chemical Reactions
Section4.9: Spectrophotometry
Problem 3.1ACP
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1.0 g of a solid sample known to contain a mixture of NaOH and Na2CO3 is dissolved with distilled water and completed to 25 mL. By adding 2 drops of phenolphthalein (pT = 9.0) to the solution obtained, it was titrated with 0.107 M calibrated HCl solution, and the consumption was determined as 10.6 mL. Subsequently, 2 drops of methyl red (pT = 4.4) were added onto the same solution and titrated, the consumption was determined as 6.1 mL. Accordingly, calculate the amount of NaOH and Na2CO3 in the sample solution as% (a/a) by writing the related reactions. (Na: 23, C: 12, O: 16, H: 1 g / mol)

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