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1/2 66.7% 玩。 1/2 66.7% 1 Divalent carbon species called corbenes are capable of fleeting existence. For example, methylene, CH, is the simplest carbene. The two unshared electrons in methylene can be either paired in a single orbital or unpaired in different orbitals. C: A metthylene Identify the type of hybridization you expect carbon to adopt in singlet (spin-paired) methylene and draw an illustration of its orbital showing the location of its electrons. b. Identify the type of hybridization you expect carbon to adopt in triplet (spin-unpaired) methylene and draw an illustration of its orbital showing the location of its electrons. a. 2. Imagine describing the bonding in ammonia as arising by overlap of the half-filled unhybridized 2px, 2py, and 2pz orbitals of nitrogen with the half-filled 1s orbitals of three hydrogen atoms. H. H H Ammonia What kind of orbital would the unshared pair occupy? b. What would you expect the bond angles to be? Draw an illustration. 3. Of the orbital overlaps shown in the illustration, one is bonding, one is antibonding, and the third is nonbonding (neither bonding nor antibonding). Which orbital overlap corresponds to which interaction? Why? L 業 II

1/2 66.7% 玩。 1/2 66.7% 1 Divalent carbon species called corbenes are capable of fleeting existence. For example, methylene, CH, is the simplest carbene. The two unshared electrons in methylene can be either paired in a single orbital or unpaired in different orbitals. C: A metthylene Identify the type of hybridization you expect carbon to adopt in singlet (spin-paired) methylene and draw an illustration of its orbital showing the location of its electrons. b. Identify the type of hybridization you expect carbon to adopt in triplet (spin-unpaired) methylene and draw an illustration of its orbital showing the location of its electrons. a. 2. Imagine describing the bonding in ammonia as arising by overlap of the half-filled unhybridized 2px, 2py, and 2pz orbitals of nitrogen with the half-filled 1s orbitals of three hydrogen atoms. H. H H Ammonia What kind of orbital would the unshared pair occupy? b. What would you expect the bond angles to be? Draw an illustration. 3. Of the orbital overlaps shown in the illustration, one is bonding, one is antibonding, and the third is nonbonding (neither bonding nor antibonding). Which orbital overlap corresponds to which interaction? Why? L 業 II

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter9: Covalent Bonding: Orbitals
Section: Chapter Questions
Problem 44E: Minoxidil (C9H15N15O) is a compound produced by the Pharmacia Upjohn Company that has been approved...
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1/2 66.7% 玩。 1/2 66.7% 1 Divalent carbon species called corbenes are capable of fleeting existence. For example, methylene, CH, is the simplest carbene. The two unshared electrons in methylene can be either paired in a single orbital or unpaired in different orbitals. C: A metthylene Identify the type of hybridization you expect carbon to adopt in singlet (spin-paired) methylene and draw an illustration of its orbital showing the location of its electrons. b. Identify the type of hybridization you expect carbon to adopt in triplet (spin-unpaired) methylene and draw an illustration of its orbital showing the location of its electrons. a. 2. Imagine describing the bonding in ammonia as arising by overlap of the half-filled unhybridized 2px, 2py, and 2pz orbitals of nitrogen with the half-filled 1s orbitals of three hydrogen atoms. H. H H Ammonia What kind of orbital would the unshared pair occupy? b. What would you expect the bond angles to be? Draw an illustration. 3. Of the orbital overlaps shown in the illustration, one is bonding, one is antibonding, and the third is nonbonding (neither bonding nor antibonding). Which orbital overlap corresponds to which interaction? Why? L 業 II
Transcribed Image Text:1/2 66.7% 玩。 1/2 66.7% 1 Divalent carbon species called corbenes are capable of fleeting existence. For example, methylene, CH, is the simplest carbene. The two unshared electrons in methylene can be either paired in a single orbital or unpaired in different orbitals. C: A metthylene Identify the type of hybridization you expect carbon to adopt in singlet (spin-paired) methylene and draw an illustration of its orbital showing the location of its electrons. b. Identify the type of hybridization you expect carbon to adopt in triplet (spin-unpaired) methylene and draw an illustration of its orbital showing the location of its electrons. a. 2. Imagine describing the bonding in ammonia as arising by overlap of the half-filled unhybridized 2px, 2py, and 2pz orbitals of nitrogen with the half-filled 1s orbitals of three hydrogen atoms. H. H H Ammonia What kind of orbital would the unshared pair occupy? b. What would you expect the bond angles to be? Draw an illustration. 3. Of the orbital overlaps shown in the illustration, one is bonding, one is antibonding, and the third is nonbonding (neither bonding nor antibonding). Which orbital overlap corresponds to which interaction? Why? L 業 II
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