12. Phenyl acetate (CaHO,) is produced by reacting phenol (CH.O) and acetic anhydride (CaH.Os). CHO (s) + CaH,O3 m + CaH,Ozm + CH,CO,H ( - You mix 100.0 g of each reactant a) What is the maximum amount of ethyl benzoate that can be obtained? b) What is the mass of the excess reagent remaining? c) If 102.09 g of ethyl benzoate was isolated, what is the yield of the reaction?

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Chapter4: Stoichiometry
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Problem 4.77PAE: The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce...
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12. Phenyl acetate (CH,o,) is produced by reacting phenol (CH.0) and acetic anhydride (CaHOs).
CHO (s) + C,H¢O3 1)
CaH,Oz m + CH,CO;H (nal
You mix 100.0 g of each reactant
a) What is the maximum amount of ethyl benzoate that can be obtained?
b) What is the mass of the excess reagent remaining?
c) If 102.09 g of ethyl benzoate was isolated, what is the yield of the reaction?
Part B Atomic Theory
IFS
13. Draw the Lewis structure for. Indicate the hybridization of the central atom and show the
geometry.
SP3da
14. Draw the structure of CH3COCH; with orbitals. Indicate the hybridization, bond angles, type of bonds.
You may have to draw two structures for clarity.
15. a) Write the electronic orbital configuration of Cu*. Is the ion diamagnetic or paramagnetic?
b) Write the electronic orbital configuration of Se4. Is the ion diamagnetic or paramagnetic?
Part C Gas Phase and Phase Equilibria
16. The root-mean-square speed of a certain gaseous oxide is 493 m/s at 20°C. What is the molecular
weight and molecular formula of the compound?
17. A salt decomposes according to 2 KCIO3 (5)
+ 2 KCIS) + 3 02 (8)
The reaction took place in an evacuated 5 L flask. After the experiment the temperature was 25°C an
the pressure inside the flask was 0.247 atm. If we neglect the volume of the solid, what mass of KCIC
(MW 122.55 g/mol) was introduced in the flask?
Transcribed Image Text:12. Phenyl acetate (CH,o,) is produced by reacting phenol (CH.0) and acetic anhydride (CaHOs). CHO (s) + C,H¢O3 1) CaH,Oz m + CH,CO;H (nal You mix 100.0 g of each reactant a) What is the maximum amount of ethyl benzoate that can be obtained? b) What is the mass of the excess reagent remaining? c) If 102.09 g of ethyl benzoate was isolated, what is the yield of the reaction? Part B Atomic Theory IFS 13. Draw the Lewis structure for. Indicate the hybridization of the central atom and show the geometry. SP3da 14. Draw the structure of CH3COCH; with orbitals. Indicate the hybridization, bond angles, type of bonds. You may have to draw two structures for clarity. 15. a) Write the electronic orbital configuration of Cu*. Is the ion diamagnetic or paramagnetic? b) Write the electronic orbital configuration of Se4. Is the ion diamagnetic or paramagnetic? Part C Gas Phase and Phase Equilibria 16. The root-mean-square speed of a certain gaseous oxide is 493 m/s at 20°C. What is the molecular weight and molecular formula of the compound? 17. A salt decomposes according to 2 KCIO3 (5) + 2 KCIS) + 3 02 (8) The reaction took place in an evacuated 5 L flask. After the experiment the temperature was 25°C an the pressure inside the flask was 0.247 atm. If we neglect the volume of the solid, what mass of KCIC (MW 122.55 g/mol) was introduced in the flask?
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