14. Here is shown a plot of the logarithm (to the base 10) of the diffusion coefficient versus reciprocal of the absolute temperature, for the diffusion of 10-15 iron in chromium. Determine values for the activation energy and preexponential. 10-16 0.55 0.60 0.65 0.70 Reciprocal temperature (1000/K) Diffusion coefficient (m²/s)
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- kindly help me with this problem Thank you! Subject: Physical Chemistry Instructions: solve as neatly as possible and show complete solution.No rounding-off for your decimals (include all decimals in your calculator in your computation). The following data were obtained for the adsorption of acetone on charcoal from an aqueous solution at 180C. Y (millimoles/g) C (millimoles/liter) 0.208 2.34 0.618 14.65 1.075 41.03 1.5 88.62 2.08 177.69 2.88 268.97 a) Find the constants k and n of the Freundlich equation. b) Find the constants a and b in the Langmuir equation. c) Find the constants k and n in the Temkin isotherm. d) Which of the isotherm fit the data best?For the 2° reaction H2(g) + I2(g) → 2HI(g) at 650 K, the collisional cross section, sigma H2-I2, is 0.36 nm2, the reducedmass is 3.32 × 10−27 kg, and the activation energy is 171 kJ mol−1. Use collision theory to calculate the rateconstant. If the actual value of the rate constant is 8.4 × 10−6 M-1s-1, determine the steric factor for this reaction.The diffusivity of iron atoms in the BCC atoms in the BCC Fe lattice is 4.2*10-23m2/sec at 400oC and 5.6*10-16m2/sec at 800oC. Calculate the activation energy in kilojoules per mole for the diffusion of iron atoms in the BCC Fe lattice in the temperature range.(upto two decimal places)
- The following data were obtained for the adsorption of acetone on charcoal from an aqueous solution at 180C. Y (millimoles/g) C (millimoles/liter) 0.208 2.34 0.618 14.65 1.075 41.03 1.5 88.62 2.08 177.69 2.88 268.97 a) Find the constants k and n of the Freundlich equation. b) Find the constants a and b in the Langmuir equation. c) Find the constants k and n in the Temkin isotherm. d) Which of the isotherm fit the data best? Answer letter D only thank you!kindly help me with this problem thank you 2. The following data are for Xenon adsorption on ZSM5 zeolite. Evaluate the constants from thea) Langmuir and b) Freundlich. Which of the isotherm fit the data best? Explain. P(Torr) 47 136 250 364 473 577 680 mass(g) of ZSM5 zeolite/mole of Xenon 1.8832 0.8977 0.6588 0.5692 0.5255 0.4946 0.4715A silver-30%gold alloy sample (cylindrical with 1 cm diameter and 0.3 cm height) is subjected to a selective silver dissolution in 0.1 M HNO3 at current density of 2.5 mA/cm2 . How long will it take until the total amount of silver is dissolved? Assume in average a density of 12 g/cm3 for the alloy sample.
- In the fluorination reaction of butadiene, the butadiene is adsorbed onto a catalyst C.To test the efficiency of the adsorption, the adsorption isotherm was determined.The volume of butadiene per gram of C varied as follows at constant temperature:p( kPa)- 13.3; 26.7 ; 40.0 ; 53.3 ; 66.7 ; 80.0V(cm3)-17.9 ; 33.0 ; 47.0 ; 60.8 ;75.3 ; 91.3At the temperature used, p* for butadiene is 200 kPa. Find a suitable isotherm for the data and determine Vmon. please assist.Ali has measured the oxidative stability of palm oil sample under accelerated storage condition at 60*C for 6 days The following data were recorded for the peroxide value and p anisidine value of the palm oil after 5 days of storage time: Sample weight 1.0030 g Concentration of NazSzO3 = 0.001 N Volume of NazSzO3 titrated for sample solution = 1.35 ml Volume of NazSzO3 titrated for blank solution 0.20 ml Absorbance for sample solution = 0.907 Absorbance for blank solution 0.203 Calculate: i) peroxide value ii) p-anisidine value iii) TOTOX valueThe following data was obtained for the adsorption of an organic compound (S), on activated carbon from an aqueous solution of molar concentration Co, at 18 °C: Data: Molecular weight of S: 58 g/molWhich isotherm best represents the data: Langmuir, Freundlich, or BET?
- In this table the Kr volume adsorbed on an active carbon surface are given, as a function of the pressures, at 193.5 K. a) Does this data fit well to a Langmuir isotherm? If yes, determine vm and b.1. What is/are the applications of the following adsorption isotherm models and their limitations? a. Langmuir b. BETFor the reduction 2FeCl3 + SnCl2 =====➔ 2 FeCl2 + SnCl4 in aqueous solution the following data were obtained at 25oC t(min) 1 3 7 11 40 Y 0.01434 0.02664 0.03612 0.04102 0.05058 Where y is the amount of FeCl3 reacted in moles per liter. The initial concentrations of SnCl3 and FeCl3 were respectively, 0.03125, 0.0625 moles/L. a.)Show that the reaction is third order (derive the rate law), and b.) calculate the average specific rate constant.