For N2 adsorbed on activated carbon at –77 °C, the following values of adsorbed gas (per gram of adsorbent) were obtained at different pressures: P/atm 3.5 10.0 16.7 25.7 33.5 39.2 v/(cm³/g) 101 136 153 162 165 166 - Estimate the volume value of the monolayer. - Calculate the coating fraction (θ) at a pressure of 10 atm. ANSWER: 0.82 - What would happen (increase / decrease) with the coating fraction at 10 atm if the temperature increased? - What would happen to the volume of the monolayer if the temperature increased? - Using the Langmuir isotherm, estimate the value of the adsorption equilibrium constant. Tip: use the overlay fraction at 10 atm (already calculated in item b) and calculate the value of K. ANSWER: 0.45
For N2 adsorbed on activated carbon at –77 °C, the following values of adsorbed gas (per gram of adsorbent) were obtained at different pressures: P/atm 3.5 10.0 16.7 25.7 33.5 39.2 v/(cm³/g) 101 136 153 162 165 166 - Estimate the volume value of the monolayer. - Calculate the coating fraction (θ) at a pressure of 10 atm. ANSWER: 0.82 - What would happen (increase / decrease) with the coating fraction at 10 atm if the temperature increased? - What would happen to the volume of the monolayer if the temperature increased? - Using the Langmuir isotherm, estimate the value of the adsorption equilibrium constant. Tip: use the overlay fraction at 10 atm (already calculated in item b) and calculate the value of K. ANSWER: 0.45
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For N2 adsorbed on activated carbon at –77 °C, the following values of adsorbed gas (per gram of adsorbent) were obtained at different pressures:
| P/atm | 3.5 | 10.0 | 16.7 | 25.7 | 33.5 | 39.2 |
| v/(cm³/g) | 101 | 136 | 153 | 162 | 165 | 166 |
- Estimate the volume value of the monolayer.
- Calculate the coating fraction (θ) at a pressure of 10 atm. ANSWER: 0.82
- What would happen (increase / decrease) with the coating fraction at 10 atm if the temperature increased?
- What would happen to the volume of the monolayer if the temperature increased?
- Using the Langmuir isotherm, estimate the value of the adsorption equilibrium constant. Tip: use the overlay fraction at 10 atm (already calculated in item b) and calculate the value of K. ANSWER: 0.45
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