The following data were obtained for the adsorption of a certain material (ORA) on activated carbon at 25 °C. Sample Activated carbon mass [ORA) initial (M) [ORA] at equilibrium (M) 0.0044 number (8) 1.0119 1 0.0096 1.0186 0.0289 0.0207 3 1.0360 0.0578 0.0446 4 1.0129 0.0867 0.0721 1.0393 0.1156 0.1002 6. 1.0312 0.1445 0.1270 7 1.0198 0.1926 0.1742 8. 1.0270 0.2407 0.2227 1.0252 0.2889 0.1108 1. Try fitting these data using Langmuir Isotherm and obtain K and monolayer of ORA molecules per one gram 2. Try fitting these data using Freundlich Isotherm and obtain its constants 3. Which isotherm describe best the adsorption of ORA on activated carbon and why? 4. If a monolayer of N2 molecules is 0.03075 mole per one gram of activated carbon, and the surface area on one N2 molecules is 0.162 nm², determine: a. surface area per one gram of activated carbon b. surface area of one ORA molecule

Fundamentals Of Analytical Chemistry
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Chapter30: Kinetic Methods Of Analysis
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The following data were obtained for the adsorption of a certain material (ORA) on activated
carbon at 25 °C.
Sample
number
Activated carbon mass
[ORA) initial (M)
(8)
1.0119
[ORA] at equilibrium
(М)
0.0044
1
0.0096
1.0186
0.0289
0.0207
1.0360
0.0578
0.0446
4
1.0129
0.0867
0.0721
1.0393
0.1156
0.1002
6.
1.0312
0.1445
0.1270
7
1.0198
0.1926
0.1742
8.
1.0270
0.2407
0.2227
1.0252
0.2889
0.1108
1. Try fitting these data using Langmuir Isotherm and obtain K and monolayer of ORA molecules
per one gram
2. Try fitting these data using Freundlich Isotherm and obtain its constants
3. Which isotherm describe best the adsorption of ORA on activated carbon and why?
4. If a monolayer of N2 molecules is 0.03075 mole per one gram of activated carbon, and the
surface area on one N2 molecules is 0.162 nm², determine:
a. surface area per one gram of activated carbon
b. surface area of one ORA molecule
Transcribed Image Text:The following data were obtained for the adsorption of a certain material (ORA) on activated carbon at 25 °C. Sample number Activated carbon mass [ORA) initial (M) (8) 1.0119 [ORA] at equilibrium (М) 0.0044 1 0.0096 1.0186 0.0289 0.0207 1.0360 0.0578 0.0446 4 1.0129 0.0867 0.0721 1.0393 0.1156 0.1002 6. 1.0312 0.1445 0.1270 7 1.0198 0.1926 0.1742 8. 1.0270 0.2407 0.2227 1.0252 0.2889 0.1108 1. Try fitting these data using Langmuir Isotherm and obtain K and monolayer of ORA molecules per one gram 2. Try fitting these data using Freundlich Isotherm and obtain its constants 3. Which isotherm describe best the adsorption of ORA on activated carbon and why? 4. If a monolayer of N2 molecules is 0.03075 mole per one gram of activated carbon, and the surface area on one N2 molecules is 0.162 nm², determine: a. surface area per one gram of activated carbon b. surface area of one ORA molecule
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