2. Draw the mechanism of free radical polymerization that produces tetramer of polyvinyl chlo- ride. Use AIBN (Q1) as to initiate the radical chain reaction. Use coupling of two tetramers to show the termination step. 3. Unsaturated fatty acids readily undergo radical-mediated peroxidation. Describe the propa- gation stage of peroxidation reaction3 by showing peroxidation of oleic acid. Peroxidation of

Organic Chemistry
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ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
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Chapter29: Organic Polymer Chemistry
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Problem 29.28P
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2. Draw the mechanism of free radical polymerization that produces tetramer of polyvinyl chlo-
ride. Use AIBN (Q1) as to initiate the radical chain reaction. Use coupling of two tetramers to
show the termination step.
3. Unsaturated fatty acids readily undergo radical-mediated peroxidation. Describe the propa-
gation stage of peroxidation reaction' by showing peroxidation of oleic acid. Peroxidation of
arachidonic acid is 200 times faster than oleic acid. Briefly explain that observation.
Transcribed Image Text:2. Draw the mechanism of free radical polymerization that produces tetramer of polyvinyl chlo- ride. Use AIBN (Q1) as to initiate the radical chain reaction. Use coupling of two tetramers to show the termination step. 3. Unsaturated fatty acids readily undergo radical-mediated peroxidation. Describe the propa- gation stage of peroxidation reaction' by showing peroxidation of oleic acid. Peroxidation of arachidonic acid is 200 times faster than oleic acid. Briefly explain that observation.
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