25 30 30 40 (5.0, 39.0) 35 35 -10 30 40- 25 - (10.0, 19.5) 20 - 15 - (15.0, 13.0) (20.0, 9.8) 10 (25.0, 7.8) (30.0, 6.5) 10 T 10 15 20 25 30 15 v (mL) 20 0.18 25 0.16 30 mL/cc 0.14 0.12 0.1 - 0.08 0.06 0.04 - 0.02 0 5 10 15 20 25 30 35 V (mL) Figure 9.13 When a gas occupies a smaller volume, it exerts a higher pressure; when it occupies a larger volume, it exerts a lower pressure (assuming the amount of gas and the temperature do not change). Since P and V are inversely proportional, a graph of - vs. V is linear. 1/P (psi) P(psi)

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter7: Statistical Data Treatment And Evaluation
Section: Chapter Questions
Problem 7.16QAP
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Question

The sample of gas as shown has a volume of 15.0 mL at a pressure of 13.0 psi. Determine the pressure of the gas at a volume of 7.5 mL, using:
(a) the P-V graph as shown.
(b) the (1P) vs. V graph as shown.
(c) the Boyle’s law equation Comment on the likely accuracy of each method.

25 30
30
40
(5.0, 39.0)
35
35
-10
30
40-
25 -
(10.0, 19.5)
20 -
15 -
(15.0, 13.0)
(20.0, 9.8)
10
(25.0, 7.8)
(30.0, 6.5)
10
T
10
15
20
25
30
15
v (mL)
20
0.18
25
0.16
30
mL/cc
0.14
0.12
0.1 -
0.08
0.06
0.04 -
0.02
0 5 10 15 20 25 30 35
V (mL)
Figure 9.13 When a gas occupies a smaller volume, it exerts a higher pressure; when it occupies a larger volume, it
exerts a lower pressure (assuming the amount of gas and the temperature do not change). Since P and V are
inversely proportional, a graph of - vs. V is linear.
1/P (psi)
P(psi)
Transcribed Image Text:25 30 30 40 (5.0, 39.0) 35 35 -10 30 40- 25 - (10.0, 19.5) 20 - 15 - (15.0, 13.0) (20.0, 9.8) 10 (25.0, 7.8) (30.0, 6.5) 10 T 10 15 20 25 30 15 v (mL) 20 0.18 25 0.16 30 mL/cc 0.14 0.12 0.1 - 0.08 0.06 0.04 - 0.02 0 5 10 15 20 25 30 35 V (mL) Figure 9.13 When a gas occupies a smaller volume, it exerts a higher pressure; when it occupies a larger volume, it exerts a lower pressure (assuming the amount of gas and the temperature do not change). Since P and V are inversely proportional, a graph of - vs. V is linear. 1/P (psi) P(psi)
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