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- Consider the Newman projection below. a. Draw a full Lewis structure of this molecule with R1=Me,R2=Et , and R3=iPr . b. Given the sizes of these R groups (R3R2R1) , does the Newman projection above show thelowest potential energy conformation of this bond? If not, draw a Newman projectionshowing the lowest P.E. conformation (sighting down this same bond). c. To draw a Newman projection in the lowest P.E. conformation, the following rule of thumbusually applies: Place the largest group on the front carbon anti to the largest group on theback carbon. Is your answer to the previous question consistent with this rule of thumb?Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.a model of cyclohexane in a chair conformation, and explain why the names “axial” and“equatorial’ are appropriate.
- Fill in the blanks: cis-1,3-Dimethylcyclohexane has two different chair conformations: one withboth methyl groups in __________ positions and one with both methyl groups in ____________ positions.Indicate the relationship between each pair. Choose from: configurational stereoisomers,conformers, constitutional isomers, or different formulas (Each term is used at least twice.)Build a model of methylcyclohexane, and use the model to complete the following Newmanprojections of methylcyclohexane in the chair conformation: a. When the methyl group is in an axial or equatorial (circle one) position, the molecule is inits lowest potential energy conformation. b. Label one Newman projection above anti and the other gauche to describe the relationshipbetween the methyl group and C3 of the ring. c. In general, which is a lower PE conformation, anti or gauche? d. Explain how your answer to b and c provide an explanation for why it is more favorable fora large group to be in an equatorial than an axial position.
- Draw both cis chair conformations of 2-methylcyclohexanol and circle the more stable one.Draw the Newman projections of the three p0ssible staggered c0nf0rmati0ns 0f 2,3-dimethylbutane, viewed through the C2—C3 b0nd. What are the relative energies 0f each conformation?Draw one chair conformer of (1S,2R,4R)-4-chloro-2-methylcyclohexan-1-ol. Include all groups of the three stereocenters, but no other hydrogens.