3. Fill out the partial C₂ character table below in five easy steps: C2h Г1 [2 T3 T4 E A. Fill in the remaining symmetry operations of the C₂ point group (E and on are provided). B. Write out 3 x 3 matrix representations for these operations using the standard Cartesian coordinates with the z-axis coincident with the C₂ axis. You should arrive at a set of block diagonalized matrices, each of which you can decompose in your head as three 1 x 1 irreducible representations. C. From these matrices, you can use two of their blocks to write out I and I2. Why can you not write out I3 from the third blocks in this instance? D. Generate I; and I, using the rules discussed in class. E. Assign proper Mulliken symbols to each irreducible representation. F. Assign the linear (R. Ry, R₂, x, y, and z) functions to the appropriate irreducible representations.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.3E: Identify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to...
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3. Fill out the partial C₂ character table below in five easy steps:
C2h E
[₁
[₂
T3
Г4
Oh
A. Fill in the remaining symmetry operations of the C2 point group (E and on are provided).
B. Write out 3 x 3 matrix representations for these operations using the standard Cartesian coordinates
with the z-axis coincident with the C₂ axis. You should arrive at a set of block diagonalized matrices,
each of which you can decompose in your head as three 1 x 1 irreducible representations.
C. From these matrices, you can use two of their blocks to write out I and I2. Why can you not write
out I3 from the third blocks in this instance?
D. Generate I and I4 using the rules discussed in class.
E. Assign proper Mulliken symbols to each irreducible representation.
F. Assign the linear (R. Ry, Rz, x, y, and z) functions to the appropriate irreducible representations.
Transcribed Image Text:3. Fill out the partial C₂ character table below in five easy steps: C2h E [₁ [₂ T3 Г4 Oh A. Fill in the remaining symmetry operations of the C2 point group (E and on are provided). B. Write out 3 x 3 matrix representations for these operations using the standard Cartesian coordinates with the z-axis coincident with the C₂ axis. You should arrive at a set of block diagonalized matrices, each of which you can decompose in your head as three 1 x 1 irreducible representations. C. From these matrices, you can use two of their blocks to write out I and I2. Why can you not write out I3 from the third blocks in this instance? D. Generate I and I4 using the rules discussed in class. E. Assign proper Mulliken symbols to each irreducible representation. F. Assign the linear (R. Ry, Rz, x, y, and z) functions to the appropriate irreducible representations.
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