4 b) At pH 1.58, calculate the free [PO43-] when [PO43-]t = 22 mM. You can either solve 4 simultaneous equations to solve this problem for [H3PO4], [H2PO4-], [HPO42-] and [PO43-], or simply calculate the ratio of the two highest concentration species at the pH of the solution, and then calculate [PO43-] from those values. What are the two highest concentration species at pH 1.58?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.20QAP
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4 b) At pH 1.58, calculate the free [PO43-] when [PO43-]t = 22 mM. You can either solve 4 simultaneous equations to solve this problem for [H3PO4], [H2PO4-], [HPO42-] and [PO43-], or simply calculate the ratio of the two highest concentration species at the pH of the solution, and then calculate [PO43-] from those values. What are the two highest concentration species at pH 1.58?
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