5.7. Which of the following reactions or reaction schemes will accomplish the following? ? а. 1. (С6H6)СН2MgBr, THF, 2. H2CrО7 b. 1. propanol, NaOH, 2. HCI с. 1. (C6H6)СH2MgBr, THF; 2. HCІ d. 1. H2SO4, H2O, 2. (C6H6)CH2MgBr, THF е. 1. DIBALH, -78°C, 2. (С6H6)СH2MgBr, THF, 3. HСІ
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- Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.What is ΔHsys for a reaction at 51.4 °C with ΔSsurr = 749 J mol-1 K-1 ? Express your answer in kJ mol-1 to at least two significant figures.At constant pressure and 25°C, what is ΔrH° for the following reaction2C2H6(g) + 7O2(g) → 4CO2(g) + H2O(l)if the complete consumption of 14.5 g of C2H6 liberates 752.3 kJ of heat energy?
- A reaction for converting ketones to lactones, called theBaeyer–Villiger reaction, is used in the manufacture of plastics and pharmaceuticals.3-Chloroperbenzoic acid is shock-sensitive, however,and prone to explode. Also, 3-chlorobenzoic acid isa waste product. An alternative process being developeduses hydrogen peroxide and a catalyst consisting of tindeposited within a solid support. The catalyst is readilyrecovered from the reaction mixture. (a) What wouldyou expect to be the other product of oxidation of theketone to lactone by hydrogen peroxide? (b) What principlesof green chemistry are addressed by use of the proposedprocess?Hexanoic acid was added to an immiscible biphasic solvent system, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D2) of hexanoic acid in water with respect to CCl4.Jansen Gas creates three types of aviation gasoline(avgas), labeled A, B, and C. It does this by blendingfour feedstocks: Alkylate; Catalytic CrackedGasoline; Straight Run Gasoline; and Isopentane.Jansen’s production manager, Dave Wagner, hascompiled the data on feedstocks and gas types inTables 4.6 and 4.7. Table 4.6 lists the availabilitiesand values of the feedstocks, as well as their keychemical properties, Reid vapor pressure, and octanerating. Table 4.7 lists the gallons required, theprices, and chemical requirements of the three gastypes. Table 4.6 Data on Feedstocks Feedstock Alkylate CCG SRG Isopentane Gallons available (1000s) 140 130 140 110 Value per gallon $4.50 $2.50 $2.25 $2.35 Reid vapor pressure 5 8 4 20 Octane (low TEL) 98 87 83 101 Octane (high TEL) 107 93 89 108 Table 4.7 Data on Gasoline Gasoline A B C Gallons required (1000s) 120 130 120 Price per gallon $3.00 $3.50 $4.00 Max Reid pressure 7 7 7 Min octane 90 97 100 TEL level Low High High Note that each feedstock…
- Given the heats of the following reactions: deltaH°(kJ) I. P4(s) + 6Cl2(g) ® 4PCl3(g) –1225.6 II. P4(s) + 5O2(g) ® P4O10(s) –2967.3 III. PCl3(g) + Cl2(g) ® PCl5(g) –84.2 IV. PCl3(g) + 1/2O2(g) ® Cl3PO(g) –285.7 Calculate the value of deltaH° for the reaction below: P4O10(s) + 6PCl5(g) ® 10Cl3PO(g) Select one: a. –110.5 kJ b. –610.1 kJ c. –2682.2 kJ d. –7555.0 kJFind out feasible reaction in high temperature gas-phase from following reactions? explain reasoning in all cases- (a) CuBr2(g) + 2NaF(g) --> CuF2(g) + 2NaBr(g) (b) TiF4(g) + 2TiI2(g)--> TiI4(g) + 2TiF2(g) (c) CuI2(g) + 2CuF(g) --> CuF2(g) + 2CuI(g) (d) CoF2(g) + HgBr2(g) --> CoBr2(g) + HgF2(g)For the reaction 5Ce4+ + Mn 2+ + 4H2 O → 5Ce3+ + MnO4- + 8H+ , given E0 (Ce4+ /Ce3+ ) = 1.70V,E0 (MnO4- /Mn2+ ) = 1.507V, calculate ΔG0 for this reaction ?
- In the synthesis of hydrocarbons, the carbon source is carbon dioxide. Although the CO2 concentra?on in the atmosphere raises at a drama?c speed, point sources are probably the easier sources for a PtX process. Iden?fy 3 possible point sources, explain why CO2 is formed and what challenges each of the three CO2 streams presentsI. Molecular rearrangements D.) How do Lewis acids help to promote reactivity and 1,2-migrations? Explain how you can use AgNO3 to coordinate with iodide to promote migrations.What is ΔSsurr for a reaction at 28.6 °C with ΔHsys = 38.9 kJ mol-1 ? Express your answer in J mol-1 K-1 to at least two significant figures.