Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter22: Organic Chemistry
Section: Chapter Questions
Problem 28QAP: When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction...
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Question
A reaction for converting
Baeyer–Villiger reaction,
is used in the manufacture of plastics and pharmaceuticals.
3-Chloroperbenzoic acid is shock-sensitive, however,
and prone to explode. Also, 3-chlorobenzoic acid is
a waste product. An alternative process being developed
uses hydrogen peroxide and a catalyst consisting of tin
deposited within a solid support. The catalyst is readily
recovered from the reaction mixture. (a) What would
you expect to be the other product of oxidation of the
ketone to lactone by hydrogen peroxide? (b) What principles
of green chemistry are addressed by use of the proposed
process?
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