TABLE16.3Formation Constants of Coordination Complexes in Aqueous SolutionK,K2K3K4K5K6AmminesAg(NH;);Co(NH;)*Cu(NH,);Ni(NH;)Zn(NH,),*1.7 x 1072.1 X 1038.2 x 1032.5 x 1041.0 X 102328.54.41.10.181.1 X 10121.0 X 1042 x 1035 x 102902+8 x 10-75 X 1085 x 1021.3 x 10240123.30.812+1.5 x 1021.8 x 1022 x 10290Chlorides1.7 x 103AgCl,FeCl,HgClPbCl?SnCl?1.8 X 1051.0 X 1020.14284.50.11.1 X 1021.2 x 10155.5 x 1063 x 10671025401.50.80.530325.40.60.3Hydroxidesзх 10103 x 10182 x 10114 × 10145 x 10148 x 1054 X 1041 x 1079 x 1047 X 107Co(OH);Cu(OH);15 x 1064 x 1032 x 1036 x 1025 x 10330Ni(OH)3Pb(OH);Zn(OH)?1.1 X 1032.5 X 1048 X 1067033 *76. Using data from Table 16.3, calculate the concentrationsof Hg²*(aq), HgCl*(aq), and HgCl2(aq) that result when1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with anequal volume of a 0.100 M HgCl, solution. (Hint: Usethe analogy with amphoteric equilibria discussed in Sec-tion 10.8.)

We have find out concentration of Hg2+, HgCl+ and HgCl2.

*76. Using data from Table 16.3, calculate the concentrations of Hg²+(aq), HgCl*(aq), and HgCl2(aq) that result when 1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with an equal volume of a 0.100 M HgCl, solution. (Hint: Use the analogy with amphoteric equilibria discussed in Sec- tion 10.8.)

76. Using data from Table 16.3, calculate the concentrations of Hg²+(aq), HgCl(aq), and HgCl2(aq) that result when 1.00 L of a 0.100 M Hg(NO3)2 solution is mixed with an equal volume of a 0.100 M HgCl, solution. (Hint: Use the analogy with amphoteric equilibria discussed in Sec- tion 10.8.)

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter16: Solubility And Precipitation Equilibria

Section: Chapter Questions

Problem 76AP

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