A 0.4126-g sample of primary-standard Na2CO3 was treated with 40.00 mL of dilute perchloric acid. The solution was boiled to remove CO2, following which the excess HClO4 was back - titrated with 9.20 mL of dilute NaOH. In a separate experiment, it was established that 26.93 mL of the HClO4 neutralized the NaOH in a 25.00-mL portion. Calculate the molarities of the HClO4 and NaOH.

A 0.4126-g sample of primary-standard Na2CO3 was treated with 40.00 mL of dilute perchloric acid. The solution was boiled to remove CO2, following which the excess HClO4 was back - titrated with 9.20 mL of dilute NaOH. In a separate experiment, it was established that 26.93 mL of the HClO4 neutralized the NaOH in a 25.00-mL portion. Calculate the molarities of the HClO4 and NaOH.

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter4: Stoichiometry: Quantitative Information About Chemical Reactions

Section4.9: Spectrophotometry

Problem 3.1ACP

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1.0 g of a solid sample known to contain a mixture of NaOH and Na2CO3 is dissolved with distilled water and completed to 25 mL. By adding 2 drops of phenolphthalein (pT = 9.0) to the solution obtained, it was titrated with 0.107 M calibrated HCl solution, and the consumption was determined as 10.6 mL. Subsequently, 2 drops of methyl red (pT = 4.4) were added onto the same solution and titrated, the consumption was determined as 6.1 mL. Accordingly, calculate the amount of NaOH and Na2CO3 in the sample solution as% (a/a) by writing the related reactions. (Na: 23, C: 12, O: 16, H: 1 g / mol)
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For breakfast, the nihilistic Rick Sanchez ate 100 g of cereal mixed with 20 g of milk. A 1.500 g sample of the same cereal was analyzed using the Kjeldahl method, and the liberated NH3 was distilled into 50 mL of a 0.0227 M HCl solution, and back-titrated with 2.85 mL of 0.0112 M NaOH solution. A 1.100 g sample of milk was also analyzed, and the liberated NH3 was distilled into 55 mL of a 0.0234 M HCl solution, and back-titrated with a 3.10 mL of 0.0121 M NaOH. Use the values: MM N=14.07 g/mol. meat= 6.25 dairy= 6.38 cereal= 5.70 What is the % protein in the cereal sample? What is the % protein in the milk sample?
For breakfast, the nihilistic Rick Sanchez ate 100 g of cereal mixed with 20 g of milk. A 1.500 g sample of the same cereal was analyzed using the Kjeldahl method, and the liberated NH3 was distilled into 50 mL of a 0.0227 M HCl solution, and back-titrated with 2.85 mL of 0.0112 M NaOH solution. A 1.100 g sample of milk was also analyzed, and the liberated NH3 was distilled into 55 mL of a 0.0234 M HCl solution, and back-titrated with a 3.10 mL of 0.0121 M NaOH. Use the values: MM N=14.07 g/mol. meat= 6.25 dairy= 6.38 cereal= 5.70 1. What is the % protein in the cereal sample? a. 5.90% protein b. 10.21% protein c. 11.80% protein d. 20.42% protein 2. What is the % protein in the milk sample? a. 5.90% protein b. 10.21% protein c. 11.80% protein d. 20.42% protein 3. How many grams of protein did Rick consume over-all? a. 3.749 g b. 7.942 g c. 5.901 g d. 10.21 g
if a 1.25g sample of magnesium oxide (98.9%) were titrated with 70ml of 1.04N of sulfuric acid, what volume of 1.15N sodium hydroxide would be required in the back titration?
Limestone consists mainly of the mineral calcite, CaCO 3. The carbonate content of 0.5413 g of powdered limestone was measured by suspending the powder in water, adding 10.00 mL of 1.396 M HCl, and heating to dissolve the solid and expel CO 2: CaCO 3(s) + 2 HCl → CaCl 2 + CO 2(g) + H 2O The excess acid required 39.96 mL of 0.1004 M NaOH for complete titration to a phenolphthalein end point. Find the weight percent of calcite in the limestone.
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